西部皮革
西部皮革
서부피혁
West Leather
2015年
18期
25-29,32
,共6页
车玮%常杰鲜%陈继平%龚英
車瑋%常傑鮮%陳繼平%龔英
차위%상걸선%진계평%공영
飞机草%亚硫酸化改性%鞣性%相对分子质量分布%多酚
飛機草%亞硫痠化改性%鞣性%相對分子質量分佈%多酚
비궤초%아류산화개성%유성%상대분자질량분포%다분
eupatorium odoratum L.%sulfitation%tanning ability%molecular weight distribution%polyphenols
菊科植物飞机草具有一定的鞣制性能,但仍存在着传统植物鞣剂增厚率太高、颜色深、收缩温度低等缺点。本文期望通过亚硫酸化改性克服上述不足。首先采用正交实验法对飞机草茎和叶提取物进行亚硫酸化改性,接着采用改性物处理酸裸皮,处理后的坯革颜色在浅黄棕到深黄棕范围变化,增厚率低于传统植鞣革,为5.0%~6.7%,收缩温度可提高37益。采用改性物与铝盐结合鞣制,坯革收缩温度可达90益,基本达到无铬鞣革的耐湿热稳定性要求。研究首次获得了飞机草亚硫酸化改性物部分理化性质及其鞣制性能,可为进一步开发这种新植物鞣剂提供一些参考。
菊科植物飛機草具有一定的鞣製性能,但仍存在著傳統植物鞣劑增厚率太高、顏色深、收縮溫度低等缺點。本文期望通過亞硫痠化改性剋服上述不足。首先採用正交實驗法對飛機草莖和葉提取物進行亞硫痠化改性,接著採用改性物處理痠裸皮,處理後的坯革顏色在淺黃棕到深黃棕範圍變化,增厚率低于傳統植鞣革,為5.0%~6.7%,收縮溫度可提高37益。採用改性物與鋁鹽結閤鞣製,坯革收縮溫度可達90益,基本達到無鉻鞣革的耐濕熱穩定性要求。研究首次穫得瞭飛機草亞硫痠化改性物部分理化性質及其鞣製性能,可為進一步開髮這種新植物鞣劑提供一些參攷。
국과식물비궤초구유일정적유제성능,단잉존재착전통식물유제증후솔태고、안색심、수축온도저등결점。본문기망통과아류산화개성극복상술불족。수선채용정교실험법대비궤초경화협제취물진행아류산화개성,접착채용개성물처리산라피,처리후적배혁안색재천황종도심황종범위변화,증후솔저우전통식유혁,위5.0%~6.7%,수축온도가제고37익。채용개성물여려염결합유제,배혁수축온도가체90익,기본체도무락유혁적내습열은정성요구。연구수차획득료비궤초아류산화개성물부분이화성질급기유제성능,가위진일보개발저충신식물유제제공일사삼고。
The composites Eupatorium odoratum L. was introduced as a kind of tanning agent, however, it was of the typical disadvantages for vegetable tannins, such as over strong thickening, deep color and low shrinkage temperature. These shortages were expected to be avoided by sulfitation in this study. Firstly, the orthogonal experiments were designed to study the sulfitation, and then these products were used to treat pickled pigskins. As proved, the treated pigskins had a light color like yellowish-brown and 5.0%-6.7%thickening rate, which was lower than that of the traditional vegetable leather. More important was that the shrinkage temperature was elevated by 37℃. Subsequently, some modified products were exploited to treat pigskins in the presence of aluminum tanning agent, and the results showed that the shrinkage temperature was elevated up to 90 ℃, which could meet with the requirement of the chrome-free tanned leather. In a word, some physical-chemical properties were obtained for the sulfited products of Eupatorium odoratum L., which would provide some basis for developing the new vegetable tanning agent.