电力科学与工程
電力科學與工程
전력과학여공정
Electric Power Science and Engineering
2015年
9期
17-21
,共5页
热重分析%燃烧特性%动力学
熱重分析%燃燒特性%動力學
열중분석%연소특성%동역학
thermogravimetry analysis%combustion characteristics%dynamics
为了充分利用淮北矿区煤矸石和洗中煤资源,采用热重分析实验研究了煤矸石与洗中煤在不同配比下的混合燃烧特性,计算燃烧特性指数。结果发现混合煤样中随着洗中煤含量的增加,煤样的着火温度均有所下降,着火指数、燃尽指数和综合燃烧特性指数均有所提高。利用Coats—Redfern积分法对燃烧过程进行动力学分析,得到了燃烧反应的活化能和频率因子等参数。结果表明混合比对反应活化能有很大影响,燃烧反应级数为1?5级时可信度最高。
為瞭充分利用淮北礦區煤矸石和洗中煤資源,採用熱重分析實驗研究瞭煤矸石與洗中煤在不同配比下的混閤燃燒特性,計算燃燒特性指數。結果髮現混閤煤樣中隨著洗中煤含量的增加,煤樣的著火溫度均有所下降,著火指數、燃儘指數和綜閤燃燒特性指數均有所提高。利用Coats—Redfern積分法對燃燒過程進行動力學分析,得到瞭燃燒反應的活化能和頻率因子等參數。結果錶明混閤比對反應活化能有很大影響,燃燒反應級數為1?5級時可信度最高。
위료충분이용회북광구매안석화세중매자원,채용열중분석실험연구료매안석여세중매재불동배비하적혼합연소특성,계산연소특성지수。결과발현혼합매양중수착세중매함량적증가,매양적착화온도균유소하강,착화지수、연진지수화종합연소특성지수균유소제고。이용Coats—Redfern적분법대연소과정진행동역학분석,득도료연소반응적활화능화빈솔인자등삼수。결과표명혼합비대반응활화능유흔대영향,연소반응급수위1?5급시가신도최고。
In order to make the best use of coal gangue and middling resource from Huaibei mining area, experi?ment on the combustion characteristics of middling and coal gangue’s mixture in different proportion was investiga?ted by thermogravimetric analyzer, the combustion characteristic indexes were calculated. The results show that with the increase of the middling in the mixed, the ignition temperature was decreased, the ignition index, burn?out index and comprehensive combustion characteristic index were improved. In addition Coats?Redfern integral method was used for combustion process in the dynamics analysis, the activation energy and frequency factor, etc. were acquired by performing the dynamic analysis. The results indicate that the blending ratio has a great influence on activation energy in the combustion process, and the highest reliability was obtained when the combustion process obeys 1?5 magnitude of chemical reaction.