当代化工
噹代化工
당대화공
Contemporary Chemical Industry
2015年
9期
2078-2080
,共3页
二元复合体系%静态吸附%吸附量
二元複閤體繫%靜態吸附%吸附量
이원복합체계%정태흡부%흡부량
SP system%Static adsorption%Adsorption capacity
为了揭示无碱二元复合体系在地层渗流过程中界面张力及体系粘度的变化情况,首先需要对二元复合体系在地层中的吸附规律进行研究。结合大庆油田储层的实际开发条件在室内模拟其油藏温度、地下水矿化度,并通过天然岩心制成油砂测定复合体系吸附量。研究结果表明:单独聚合物体系,当浓度低于1000 mg/L时聚合物的吸附量与其浓度成线性递增规律,后随浓度的增加呈平缓变化;单独表面活性剂体系,当浓度低于临界胶束浓度(CMC 值)吸附量线性增加至峰值,后呈小幅度降低最终至平缓。由于聚/表二元复合驱油体系中聚合物的加入,在竞争吸附中可以减少了表面活性剂的吸附量。
為瞭揭示無堿二元複閤體繫在地層滲流過程中界麵張力及體繫粘度的變化情況,首先需要對二元複閤體繫在地層中的吸附規律進行研究。結閤大慶油田儲層的實際開髮條件在室內模擬其油藏溫度、地下水礦化度,併通過天然巖心製成油砂測定複閤體繫吸附量。研究結果錶明:單獨聚閤物體繫,噹濃度低于1000 mg/L時聚閤物的吸附量與其濃度成線性遞增規律,後隨濃度的增加呈平緩變化;單獨錶麵活性劑體繫,噹濃度低于臨界膠束濃度(CMC 值)吸附量線性增加至峰值,後呈小幅度降低最終至平緩。由于聚/錶二元複閤驅油體繫中聚閤物的加入,在競爭吸附中可以減少瞭錶麵活性劑的吸附量。
위료게시무감이원복합체계재지층삼류과정중계면장력급체계점도적변화정황,수선수요대이원복합체계재지층중적흡부규률진행연구。결합대경유전저층적실제개발조건재실내모의기유장온도、지하수광화도,병통과천연암심제성유사측정복합체계흡부량。연구결과표명:단독취합물체계,당농도저우1000 mg/L시취합물적흡부량여기농도성선성체증규률,후수농도적증가정평완변화;단독표면활성제체계,당농도저우림계효속농도(CMC 치)흡부량선성증가지봉치,후정소폭도강저최종지평완。유우취/표이원복합구유체계중취합물적가입,재경쟁흡부중가이감소료표면활성제적흡부량。
In order to reveal the change law of interfacial tension and viscosity in the seepage flow process of two element compound system in the formation, the adsorption regularity of the SP system was studied. Combined with the actual development conditions of Daqing oil field, reservoir temperature, groundwater salinity and natural oil sand were simulated to determine the adsorption capacity of composite system. The results show that: for single polymer system, the adsorption capacity of the polymer is linear with the concentration when the concentration is lower than of 1 000 mg/L,then the change is mild with the concentration increasing; for single surfactant system, when the concentration is lower than the critical micelle concentration (CMC), the adsorption capacity of the surfactant system linearly increases to a peak value, and then decreases to a moderate extent. Due to the polymer adding in polymer /surfactant binary combination flooding oil system, the competitive adsorption action can reduce the adsorption quantity of surface active agent.