化工学报
化工學報
화공학보
CIESC Jorunal
2015年
10期
4047-4060
,共14页
王为国%罗旌崧%曾真%王存文%吴元欣%覃远航
王為國%囉旌崧%曾真%王存文%吳元訢%覃遠航
왕위국%라정숭%증진%왕존문%오원흔%담원항
提馏式间歇精馏%优化操作%汽化总量%模拟%能耗
提餾式間歇精餾%優化操作%汽化總量%模擬%能耗
제류식간헐정류%우화조작%기화총량%모의%능모
stripping batch distillation%optimal operation%total evaporation%simulation%energy consumption
理想操作条件下二元提馏式间歇精馏优化操作的汽化总量与最小汽化总量的计算是约束函数优化问题。本文采用罚函数法,将此约束函数优化转变为无约束函数优化,并采用固定双步长因子梯度法数值求解该函数的极值。计算表明:固定双步长因子梯度法具有良好的收敛性,同时,降低分段数较多时,数值截断误差积累对计算结果的影响。二元提馏式间歇精馏优化操作较恒残液组成操作的能耗低的原因如下:在理论板数相对较少(接近二元提馏式间歇精馏恒残液组成操作所需的最少理论板)时,优化操作通过控制再沸比提高了能耗效率;在理论板数相对较多时,优化操作通过控制再沸比,在保证过程的能耗效率较高的同时,可尽可能快地将物料移出系统,减少了精馏过程中塔顶贮槽内液体的混合熵产。通过对计算结果的归纳与外推,得到了理想操作条件下理论板数为无穷多时二元提馏式间歇精馏优化操作再沸比的变化方式以及最小汽化总量的计算公式。
理想操作條件下二元提餾式間歇精餾優化操作的汽化總量與最小汽化總量的計算是約束函數優化問題。本文採用罰函數法,將此約束函數優化轉變為無約束函數優化,併採用固定雙步長因子梯度法數值求解該函數的極值。計算錶明:固定雙步長因子梯度法具有良好的收斂性,同時,降低分段數較多時,數值截斷誤差積纍對計算結果的影響。二元提餾式間歇精餾優化操作較恆殘液組成操作的能耗低的原因如下:在理論闆數相對較少(接近二元提餾式間歇精餾恆殘液組成操作所需的最少理論闆)時,優化操作通過控製再沸比提高瞭能耗效率;在理論闆數相對較多時,優化操作通過控製再沸比,在保證過程的能耗效率較高的同時,可儘可能快地將物料移齣繫統,減少瞭精餾過程中塔頂貯槽內液體的混閤熵產。通過對計算結果的歸納與外推,得到瞭理想操作條件下理論闆數為無窮多時二元提餾式間歇精餾優化操作再沸比的變化方式以及最小汽化總量的計算公式。
이상조작조건하이원제류식간헐정류우화조작적기화총량여최소기화총량적계산시약속함수우화문제。본문채용벌함수법,장차약속함수우화전변위무약속함수우화,병채용고정쌍보장인자제도법수치구해해함수적겁치。계산표명:고정쌍보장인자제도법구유량호적수렴성,동시,강저분단수교다시,수치절단오차적루대계산결과적영향。이원제류식간헐정류우화조작교항잔액조성조작적능모저적원인여하:재이론판수상대교소(접근이원제류식간헐정류항잔액조성조작소수적최소이론판)시,우화조작통과공제재비비제고료능모효솔;재이론판수상대교다시,우화조작통과공제재비비,재보증과정적능모효솔교고적동시,가진가능쾌지장물료이출계통,감소료정류과정중탑정저조내액체적혼합적산。통과대계산결과적귀납여외추,득도료이상조작조건하이론판수위무궁다시이원제류식간헐정류우화조작재비비적변화방식이급최소기화총량적계산공식。
Under ideal operation conditions, the calculation for total evaporation and the minimum total evaporation of binary stripping batch distillation under optimal operations is a constrained function optimization problem. In this work, the constrained function optimization problem is transformed to an unconstrained function optimization problem based on the penalty function method and the fixed double step length factor gradient method is used to solve the unconstrained optimization problem. The calculations show that the fixed double step length factor gradient method has good convergence, and the effect of numerical truncation error accumulation on the calculation results is reduced when the number of segments is large. The energy consumption of binary stripping batch distillation under optimal operation is lower than that under constant residual fraction composition operation. It may be attributed to the following reasons: when the theoretical plate number is relatively small (close to the minimum theoretical plate number required for binary stripping batch distillation under constant residual fraction composition operation), the energy efficiency is improved because of controllable reboil ratio under the optimal operation; when the theoretical plate number is relatively large, the entropy generation in liquid mixing in the top tank is reduced because the material is removed out of the distillation system as soon as possible in the premise of relatively high energy efficiency under the optimal operation because of the controllable reboil ratio. Under ideal operating conditions and infinite number of theoretical plates, the change strategy of the reboil ratio and the calculation formula of the minimum total evaporation of binary stripping batch distillation under optimal operation are obtained by summarizing and extrapolating the above calculation results.