吉林大学学报(地球科学版)
吉林大學學報(地毬科學版)
길림대학학보(지구과학판)
Journal of Jilin University (Earth Science Edition)
2015年
5期
1352-1364
,共13页
毛毳%陈勇%周瑶琪%葛云锦%王有智%周振柱
毛毳%陳勇%週瑤琪%葛雲錦%王有智%週振柱
모취%진용%주요기%갈운금%왕유지%주진주
烃类包裹体%盐水包裹体%合成包裹体%捕获温度%捕获压力%PIT模拟
烴類包裹體%鹽水包裹體%閤成包裹體%捕穫溫度%捕穫壓力%PIT模擬
경류포과체%염수포과체%합성포과체%포획온도%포획압력%PIT모의
hydrocarbon inclusion%aqueous inclusions%synthetic inclusions%trapping temperature%trapping pressure%PIT simulation
烃类包裹体成分和热力学行为非常复杂,准确恢复捕获条件一直是一个难点。以往的研究一般用盐水包裹体的均一温度来代替捕获温度,但是均一温度和捕获温度之间有误差,用均一温度代替捕获温度不够准确,因此需要校正。笔者对烃类和同期盐水包裹体的均一温度先校正后模拟,减少了烃类包裹体热力学模拟误差;通过对储层流体包裹体进行显微荧光、显微测温、显微共聚焦激光扫描、显微傅里叶变换红外光谱等实验分析,得到流体包裹体均一温度(90~170℃)、盐度(0.71%~11.1%)、气液比(7%~9%)、CH4的摩尔分数(20%~25%)和 CH2/CH3(4~8)等参数;结合盐水包裹体均一温度校正曲线,利用FIT‐Oil 软件进行 PIT (烃类包裹体热力学)模拟,恢复储层包裹体的捕获压力和捕获温度,提高了包裹体捕获条件获得的精度。为了验证此方法的准确性,以人工合成包裹体作为标准样品,获得盐水包裹体均一温度与捕获温度关系校正曲线,参数校正后利用软件计算出的捕获温压与实验设定的温压条件吻合良好。以东营凹陷丰深10井沙四下亚段储层包裹体为实例,进行了古温压和成藏期的估算,与前人通过其他方法得出的结论一致,证实了捕获条件获得的准确性。
烴類包裹體成分和熱力學行為非常複雜,準確恢複捕穫條件一直是一箇難點。以往的研究一般用鹽水包裹體的均一溫度來代替捕穫溫度,但是均一溫度和捕穫溫度之間有誤差,用均一溫度代替捕穫溫度不夠準確,因此需要校正。筆者對烴類和同期鹽水包裹體的均一溫度先校正後模擬,減少瞭烴類包裹體熱力學模擬誤差;通過對儲層流體包裹體進行顯微熒光、顯微測溫、顯微共聚焦激光掃描、顯微傅裏葉變換紅外光譜等實驗分析,得到流體包裹體均一溫度(90~170℃)、鹽度(0.71%~11.1%)、氣液比(7%~9%)、CH4的摩爾分數(20%~25%)和 CH2/CH3(4~8)等參數;結閤鹽水包裹體均一溫度校正麯線,利用FIT‐Oil 軟件進行 PIT (烴類包裹體熱力學)模擬,恢複儲層包裹體的捕穫壓力和捕穫溫度,提高瞭包裹體捕穫條件穫得的精度。為瞭驗證此方法的準確性,以人工閤成包裹體作為標準樣品,穫得鹽水包裹體均一溫度與捕穫溫度關繫校正麯線,參數校正後利用軟件計算齣的捕穫溫壓與實驗設定的溫壓條件吻閤良好。以東營凹陷豐深10井沙四下亞段儲層包裹體為實例,進行瞭古溫壓和成藏期的估算,與前人通過其他方法得齣的結論一緻,證實瞭捕穫條件穫得的準確性。
경류포과체성분화열역학행위비상복잡,준학회복포획조건일직시일개난점。이왕적연구일반용염수포과체적균일온도래대체포획온도,단시균일온도화포획온도지간유오차,용균일온도대체포획온도불구준학,인차수요교정。필자대경류화동기염수포과체적균일온도선교정후모의,감소료경류포과체열역학모의오차;통과대저층류체포과체진행현미형광、현미측온、현미공취초격광소묘、현미부리협변환홍외광보등실험분석,득도류체포과체균일온도(90~170℃)、염도(0.71%~11.1%)、기액비(7%~9%)、CH4적마이분수(20%~25%)화 CH2/CH3(4~8)등삼수;결합염수포과체균일온도교정곡선,이용FIT‐Oil 연건진행 PIT (경류포과체열역학)모의,회복저층포과체적포획압력화포획온도,제고료포과체포획조건획득적정도。위료험증차방법적준학성,이인공합성포과체작위표준양품,획득염수포과체균일온도여포획온도관계교정곡선,삼수교정후이용연건계산출적포획온압여실험설정적온압조건문합량호。이동영요함봉심10정사사하아단저층포과체위실례,진행료고온압화성장기적고산,여전인통과기타방법득출적결론일치,증실료포획조건획득적준학성。
Composition and thermodynamic behavior of hydrocarbon are complicated ;so it is difficult to recover its trapping conditions .In this paper ,by ways of petroleum inclusions and the corresponding period aqueous inclusions homogenization temperature correction before simulation , we reduced the petroleum inclusions thermodynamic error , increased the accuracy of trapping conditions . Through microthermometry ,fluorescence spectroscopy ,confocal scanning laser microscopy ,and Fourier transform infrared spectrum analysis we obtained the homogenization temperature(90 170 ℃ ) ,salinity (0 .71%11 .1% ) ,gas and fluid ratio(7% 9% ) ,and mole percent content of CH4 (20% 25% ) ,CH2 /CH3 (4 8) of reservoir fluid inclusions .Based on these thermodynamic parameters ,using PIT simulated data of FIT Oil and aqueous inclusions homogenization temperature calibration curve ,we recovered the trapping pressure(22 27 Mpa) and temperature(125 157 ℃ )of reservoir inclusions .By taking the synthetic hydrocarbon inclusion as a standard sample ,we applied the PIT to the reservoir fluid inclusions of Fengshen 10 well in Dongying sag Es4 x to estimate the original temperature , pressure , and the accumulation period ;by which the accuracy of the PIT method is verified .Because of its high effectivity that determine period of hydrocarbon accumulation , the method can be applied widely in various oil fields .