化工学报
化工學報
화공학보
CIESC Jorunal
2015年
10期
4252-4257
,共6页
聚乳酸%超临界流体%聚合物加工%交联剂%流变学%泡孔结构
聚乳痠%超臨界流體%聚閤物加工%交聯劑%流變學%泡孔結構
취유산%초림계류체%취합물가공%교련제%류변학%포공결구
polylactic acid%supercritical fluid%polymer processing%crosslinking agent%rheology%cellular structure
在研究交联剂对聚乳酸(PLA)流变性能影响的基础上,采用间歇发泡方法研究交联PLA发泡材料的泡孔结构。结果表明,交联剂可提高低频区PLA的损耗角正切和复数黏度以及PLA的熔体强度和拉伸黏度。交联PLA的复数黏度高,使泡孔长大初期的长大速率较低;泡孔长大后期泡孔壁被拉伸时,熔体强度和拉伸黏度的急剧提高使泡孔壁强度增加而不会被撕裂,大大减小泡孔的合并,形成较均匀且较规则的泡孔结构。交联PLA高的熔体强度可明显减少发泡时二氧化碳扩散至空气中的量,从而增加PLA发泡样品的体积膨胀率;加入0.4 phr的交联剂时,样品的体积膨胀率最大(达41)。
在研究交聯劑對聚乳痠(PLA)流變性能影響的基礎上,採用間歇髮泡方法研究交聯PLA髮泡材料的泡孔結構。結果錶明,交聯劑可提高低頻區PLA的損耗角正切和複數黏度以及PLA的鎔體彊度和拉伸黏度。交聯PLA的複數黏度高,使泡孔長大初期的長大速率較低;泡孔長大後期泡孔壁被拉伸時,鎔體彊度和拉伸黏度的急劇提高使泡孔壁彊度增加而不會被撕裂,大大減小泡孔的閤併,形成較均勻且較規則的泡孔結構。交聯PLA高的鎔體彊度可明顯減少髮泡時二氧化碳擴散至空氣中的量,從而增加PLA髮泡樣品的體積膨脹率;加入0.4 phr的交聯劑時,樣品的體積膨脹率最大(達41)。
재연구교련제대취유산(PLA)류변성능영향적기출상,채용간헐발포방법연구교련PLA발포재료적포공결구。결과표명,교련제가제고저빈구PLA적손모각정절화복수점도이급PLA적용체강도화랍신점도。교련PLA적복수점도고,사포공장대초기적장대속솔교저;포공장대후기포공벽피랍신시,용체강도화랍신점도적급극제고사포공벽강도증가이불회피시렬,대대감소포공적합병,형성교균균차교규칙적포공결구。교련PLA고적용체강도가명현감소발포시이양화탄확산지공기중적량,종이증가PLA발포양품적체적팽창솔;가입0.4 phr적교련제시,양품적체적팽창솔최대(체41)。
Abstracts: Based on the effects of crosslinking agent on the rheological properties of polylactic acid (PLA), the cellular structure of crosslinked PLA foams was investigatedvia batch foaming. The results showed that when adding the crosslinking agent to the PLA, its loss tangent and complex viscosity in low frequency region and its melt strength and extensional viscosity increased. In the initial cell growth stage, the cell wall was stretched, which dramatically increased the high complex viscosity of the crosslinked PLA slowed down the cell growth rate. In the later cell growth stage, the melt strength and extensional viscosity and so increased the strength of the cell wall. Then, cell coalescence was abviously reduced and the cellular structure of the crosslinked PLA foam samples was more regular and uniform. The amount of gas loss decreased because of the high melt strength of the crosslinked PLA, which resulted in an increased expansion ratio of the PLA foam samples. The PLA foam had a maximum volume expansion ratio of 41 when adding 0.4 phr crosslinking agent.