燃料化学学报
燃料化學學報
연료화학학보
Journal of Fuel Chemistry and Technology
2015年
9期
1134-1141
,共8页
张月%李文瀚%王春波%刘慧敏%张永生%潘伟平
張月%李文瀚%王春波%劉慧敏%張永生%潘偉平
장월%리문한%왕춘파%류혜민%장영생%반위평
气相砷%吸附剂%吸附温度%SO2/NO
氣相砷%吸附劑%吸附溫度%SO2/NO
기상신%흡부제%흡부온도%SO2/NO
gas-phase As2 O3%adsorbent%adsorption temperature%SO2/NO
使用超声波辅助浸渍法制备Fe2 O3/γ-Al2 O3吸附材料,在固定床反应器上研究了前驱液浸渍浓度、载体粒径、吸附温度、吸附气氛等因素对脱除气相As2 O3的影响。结果表明,前驱液浸渍浓度、载体粒径等会对吸附剂表面结构产生影响从而影响其砷吸附性能;吸附温度升高增强了其化学吸附能力,然而,温度过高反而造成吸附性能的下降;吸附气氛中的SO2促进了Fe2 O3/γ-Al2 O3对气相砷的吸附,气氛中的NO对气相砷的影响不大。
使用超聲波輔助浸漬法製備Fe2 O3/γ-Al2 O3吸附材料,在固定床反應器上研究瞭前驅液浸漬濃度、載體粒徑、吸附溫度、吸附氣氛等因素對脫除氣相As2 O3的影響。結果錶明,前驅液浸漬濃度、載體粒徑等會對吸附劑錶麵結構產生影響從而影響其砷吸附性能;吸附溫度升高增彊瞭其化學吸附能力,然而,溫度過高反而造成吸附性能的下降;吸附氣氛中的SO2促進瞭Fe2 O3/γ-Al2 O3對氣相砷的吸附,氣氛中的NO對氣相砷的影響不大。
사용초성파보조침지법제비Fe2 O3/γ-Al2 O3흡부재료,재고정상반응기상연구료전구액침지농도、재체립경、흡부온도、흡부기분등인소대탈제기상As2 O3적영향。결과표명,전구액침지농도、재체립경등회대흡부제표면결구산생영향종이영향기신흡부성능;흡부온도승고증강료기화학흡부능력,연이,온도과고반이조성흡부성능적하강;흡부기분중적SO2촉진료Fe2 O3/γ-Al2 O3대기상신적흡부,기분중적NO대기상신적영향불대。
Ultrasound-assisted wet impregnation method was used to prepare the Fe2 O3/γ-Al2 O3 sorbent. The effects of the precursor solution content, carrier size, adsorption temperature and atmosphere on the arsenic capture efficiency in a fixed-bed reactor were investigated. The results show that the precursor solution concentration and the size of carrier can affect the arsenic adsorption efficiency. The increasing of adsorption temperature enhances the chemical adsorption ability. However, the efficiency will be decreased if the temperature is over 600℃. The addition of SO2 in the atmosphere will enhance the arsenic adsorption ability of Fe2 O3/γ-Al2 O3 . The influence of NO on the capture efficiency is not significant during this study.