CAJ | 학술논문

采用溶剂热方法，利用柔性的配体4′-[4-methyl-6-（1-methyl-1H-benzimidazoly-l-2-group）-2-n-propyl-1H-benzimidazolylmethyl]-biphenyl-2-carboxylic acid（HL）制备了一个新颖的配合物｛Cd（L）2｝n（1）。配合物1是二维网状结构，并且在氢键和π···π键的共同作用下形成了一个三维的超分子结构。在室温条件下，配合物1和配体比较，表现出了较弱的荧光特性。
채용용제열방법，이용유성적배체4′-[4-methyl-6-（1-methyl-1H-benzimidazoly-l-2-group）-2-n-propyl-1H-benzimidazolylmethyl]-biphenyl-2-carboxylic acid（HL）제비료일개신영적배합물｛Cd（L）2｝n（1）。배합물1시이유망상결구，병차재경건화π···π건적공동작용하형성료일개삼유적초분자결구。재실온조건하，배합물1화배체비교，표현출료교약적형광특성。
A new complex{Cd(L)2}n(1)has been synthesized under solvothermal condition based on the flexible ligand 4′-[4-methyl-6-(1-methyl-1H-benzimidazoly-l-2-group)-2-n-propyl-1H-benzimidazolylmethyl]-biphenyl-2-carboxylic acid(HL). X-ray analysis demonstrates that 1 is 2D structure and is further extended into 3D supramolecular architecture by hydrogen bonds andπ···πinteractions. 1 exhibits weak luminescence emission in the solid state at room temperature.