工程塑料应用
工程塑料應用
공정소료응용
Engineering Plastics Application
2015年
9期
134-137
,共4页
李璟%欧保全%焦立才%刘怡
李璟%歐保全%焦立纔%劉怡
리경%구보전%초립재%류이
尼龙6%氮化硼%超细金属氧化物%力学性能%热导率
尼龍6%氮化硼%超細金屬氧化物%力學性能%熱導率
니룡6%담화붕%초세금속양화물%역학성능%열도솔
nylon 6%boron nitride%supper fine metallic oxide%mechanical property%thermal conductivity
为了提高尼龙6(PA6)的热导率,采用氮化硼与超细金属氧化物复配作为导热填料,制备了PA6导热复合材料,其中超细金属氧化物与氮化硼在高速混合机中混合,研究了复配填料对复合材料力学性能和热导率的影响。结果表明,随氮化硼用量的增加,复合材料的拉伸强度和弯曲强度下降不大,而冲击强度下降明显,弯曲弹性模量明显增加,当复配填料质量分数为50%时,复合材料的拉伸强度、弯曲强度、冲击强度和弯曲弹性模量分别为68.9 MPa,106.8 MPa,14.1 kJ/m2,12.7 GPa。复配填料的加入能够显著提高复合材料的热导率,当复配填料的质量分数为50%时,复合材料的层内热导率和层间热导率分别为4.578 W/(m·K)和0.456 W/(m·K)。
為瞭提高尼龍6(PA6)的熱導率,採用氮化硼與超細金屬氧化物複配作為導熱填料,製備瞭PA6導熱複閤材料,其中超細金屬氧化物與氮化硼在高速混閤機中混閤,研究瞭複配填料對複閤材料力學性能和熱導率的影響。結果錶明,隨氮化硼用量的增加,複閤材料的拉伸彊度和彎麯彊度下降不大,而遲擊彊度下降明顯,彎麯彈性模量明顯增加,噹複配填料質量分數為50%時,複閤材料的拉伸彊度、彎麯彊度、遲擊彊度和彎麯彈性模量分彆為68.9 MPa,106.8 MPa,14.1 kJ/m2,12.7 GPa。複配填料的加入能夠顯著提高複閤材料的熱導率,噹複配填料的質量分數為50%時,複閤材料的層內熱導率和層間熱導率分彆為4.578 W/(m·K)和0.456 W/(m·K)。
위료제고니룡6(PA6)적열도솔,채용담화붕여초세금속양화물복배작위도열전료,제비료PA6도열복합재료,기중초세금속양화물여담화붕재고속혼합궤중혼합,연구료복배전료대복합재료역학성능화열도솔적영향。결과표명,수담화붕용량적증가,복합재료적랍신강도화만곡강도하강불대,이충격강도하강명현,만곡탄성모량명현증가,당복배전료질량분수위50%시,복합재료적랍신강도、만곡강도、충격강도화만곡탄성모량분별위68.9 MPa,106.8 MPa,14.1 kJ/m2,12.7 GPa。복배전료적가입능구현저제고복합재료적열도솔,당복배전료적질량분수위50%시,복합재료적층내열도솔화층간열도솔분별위4.578 W/(m·K)화0.456 W/(m·K)。
In order to increase the thermal conductivity of nylon 6(PA6),boron nitride and supper fine metallic oxide were used as thermal conductive fillers to produce PA6 thermal conductive composites. The supper fine metallic oxide was mixed with boron nitride in high speed mixer. Influences of the compound fillers on thermal conductivities and mechanical properties of the composites were investigated.The results indicate that by the increase of the compound fillers,the tensile strength and flexural strength of the composites decrease slightly,butthe impact strength decreases obviously and flexural modulus increases significantly. When the mass fraction of the compound fillers is 50%,the tensile strength, flexural strength, impact strength and flexural modulus are 68.9 MPa,106.8 MPa,14.1 kJ/m2 and 12.7 GPa respectively. The conductivity of the composite can increase obviously by adding the compound fillers,In-plane thermal conductivity and through-plane thermal conductivity are 4.578 W/(m·K) and 0.456 W/(m·K) when the mass fraction of the compound fillers is 50%.