CAJ | 학술논문

利用联机电脑系统实时监测了高压反应釜内Al0.5 Mg0.5/H2 O体系的反应过程，针对反应体系的T-t曲线进行分析，提取并定义了反应过程的三个特征温度点和三个特征参数，从而建立了Al0.5 Mg0.5/H2 O反应的评价体系，作为评价Al0.5 Mg0.5/H2 O体系反应性能的标准。根据此方法，分析研究了粉末粒径、存储条件、加热功率和水燃摩尔比对Al0.5 Mg0.5/H2 O反应特性的影响，得出体系的最佳反应条件。结果表明，粒径为500目的合金粉末放热性能最好，密封存储的合金放热更加完全，合金粉末具有更高的转化率；高功率加热条件使得体系能够在更短时间内开始反应，更有利于激发反应体系进行集中高效释放能量； Al0.5 Mg0.5/H2 O体系的最佳水燃摩尔比为1.75：1。
이용련궤전뇌계통실시감측료고압반응부내Al0.5 Mg0.5/H2 O체계적반응과정，침대반응체계적T-t곡선진행분석，제취병정의료반응과정적삼개특정온도점화삼개특정삼수，종이건립료Al0.5 Mg0.5/H2 O반응적평개체계，작위평개Al0.5 Mg0.5/H2 O체계반응성능적표준。근거차방법，분석연구료분말립경、존저조건、가열공솔화수연마이비대Al0.5 Mg0.5/H2 O반응특성적영향，득출체계적최가반응조건。결과표명，립경위500목적합금분말방열성능최호，밀봉존저적합금방열경가완전，합금분말구유경고적전화솔；고공솔가열조건사득체계능구재경단시간내개시반응，경유리우격발반응체계진행집중고효석방능량； Al0.5 Mg0.5/H2 O체계적최가수연마이비위1.75：1。
The computer system was employed to monitor the reaction processes of Al0. 5 Mg0. 5/H2 O systems and the T-t curves of the Al0. 5 Mg0. 5/H2 O reaction systems were analyzed. Three characteristic temperature points and three reaction characteristics were extracted and defined. An evaluation system of Al0. 5 Mg0. 5/H2 O reactions based on these was established to study the properties of the systems. The effects of particle size, storage condition, heating power, and mole ratio of Al0. 5 Mg0. 5/H2 O were investigated according to the established evaluation standard. The results showed that the 500-mesh Al0. 5 Mg0. 5 alloy powder had the best heat release performance. Sealed storage alloy could release heat more completely. High heating power could facilitate the reaction of the systems in a shorter time and was conductive to the concentrated and efficient heat release. It was observed that the best mole ration of H2 O/Al0. 5 Mg0. 5 in the reation system was 1. 75:1.