哈尔滨工程大学学报
哈爾濱工程大學學報
합이빈공정대학학보
Journal of Harbin Engineering University
2015年
10期
1417-1420
,共4页
石墨烯%碳纳米纤维%纳米纸%形状记忆聚合物%复合材料
石墨烯%碳納米纖維%納米紙%形狀記憶聚閤物%複閤材料
석묵희%탄납미섬유%납미지%형상기억취합물%복합재료
graphene%carbon nanofiber%nanopaper%buckypaper shape memory polymer%composites
为了研究不同质量比例石墨烯( few-layer graphene, FLG)和碳纳米纤维( carbon nanofiber, CNF)对混杂FLG/CNF巴基纸导电性能的影响,测量了FLG/CNF的质量比例由0提高至50%时巴基纸的体积电阻率,并检测了混杂FLG/CNF巴基纸的微观形态,通过实验还研究了FLG/CNF巴基纸增强形状记忆聚合物复合材料的电致驱动效应及温度场分布情况. 试验结果表明:FLG/CNF巴基纸中碳纳米纤维填充了石墨烯片层间的空隙,碳纳米纤维和石墨烯片相互搭接形成连续网络;此外,巴基纸中碳纳米纤维和石墨烯比例的变化可导致巴基纸的电阻值发生改变. 巴基纸增强形状记忆聚合物复合材料在90 s时完成了形状恢复,和试样初始形状相比,试样形状约恢复了95%.
為瞭研究不同質量比例石墨烯( few-layer graphene, FLG)和碳納米纖維( carbon nanofiber, CNF)對混雜FLG/CNF巴基紙導電性能的影響,測量瞭FLG/CNF的質量比例由0提高至50%時巴基紙的體積電阻率,併檢測瞭混雜FLG/CNF巴基紙的微觀形態,通過實驗還研究瞭FLG/CNF巴基紙增彊形狀記憶聚閤物複閤材料的電緻驅動效應及溫度場分佈情況. 試驗結果錶明:FLG/CNF巴基紙中碳納米纖維填充瞭石墨烯片層間的空隙,碳納米纖維和石墨烯片相互搭接形成連續網絡;此外,巴基紙中碳納米纖維和石墨烯比例的變化可導緻巴基紙的電阻值髮生改變. 巴基紙增彊形狀記憶聚閤物複閤材料在90 s時完成瞭形狀恢複,和試樣初始形狀相比,試樣形狀約恢複瞭95%.
위료연구불동질량비례석묵희( few-layer graphene, FLG)화탄납미섬유( carbon nanofiber, CNF)대혼잡FLG/CNF파기지도전성능적영향,측량료FLG/CNF적질량비례유0제고지50%시파기지적체적전조솔,병검측료혼잡FLG/CNF파기지적미관형태,통과실험환연구료FLG/CNF파기지증강형상기억취합물복합재료적전치구동효응급온도장분포정황. 시험결과표명:FLG/CNF파기지중탄납미섬유전충료석묵희편층간적공극,탄납미섬유화석묵희편상호탑접형성련속망락;차외,파기지중탄납미섬유화석묵희비례적변화가도치파기지적전조치발생개변. 파기지증강형상기억취합물복합재료재90 s시완성료형상회복,화시양초시형상상비,시양형상약회복료95%.
In order to study the effect of few-layer graphene ( FLG) and carbon nanofiber ( CNF) on the electrical conductivity of mixed FLG/CNF buckypaper, the volume resistivity of buckypaper was measured as the quality ratio of FLG/CNF increased from 0 to 50%. The microcosmic morphology of FLG/CNF buckypaper was observed using a scanning electron microscope. The electrical actuation and the temperature distribution of the shape memory polymer ( SMP ) composites reinforced by FLG/CNF buckypaper were also tested. The results show that CNF bridged the gaps between the FLG layers, and an entangled and continuous network of FLG and CNF is observed. Furthermore, the ratio changes between FLG and CNF in the buckypaper can lead to change in the electrical resistivity of the buckypaper. The shape recovery of SMP composites reinforced by buckypaper is completed at about 90 s. The re-covered shape of the specimen is approximately 95% similar to its original shape.