CAJ | 학술논문

通过反相悬浮聚合法制备了三聚氰胺甲醛（ MF）树脂微胶囊包覆红磷，采用红外光谱（ FI-IR）、扫描电子显微镜（SEM）、X-射线光电子能谱（XPS）对其结构进行了表征，并对微胶囊红磷与聚丙烯（PP）及尼龙6（PA6）形成的复合物的极限氧指数进行了分析，评价了微胶囊红磷的热性能，测试了其在PP及PA6复合物中的阻燃效率．实验结果表明，三聚氰胺甲醛树脂被成功包覆在红磷颗粒的表面．当微胶囊红磷的添加质量分数为15％时，PA6／MRP的极限氧指数LOI大于28．2％，而PP／MRP的极限氧指数LOI大于22．4％．
통과반상현부취합법제비료삼취청알갑철（ MF）수지미효낭포복홍린，채용홍외광보（ FI-IR）、소묘전자현미경（SEM）、X-사선광전자능보（XPS）대기결구진행료표정，병대미효낭홍린여취병희（PP）급니룡6（PA6）형성적복합물적겁한양지수진행료분석，평개료미효낭홍린적열성능，측시료기재PP급PA6복합물중적조연효솔．실험결과표명，삼취청알갑철수지피성공포복재홍린과립적표면．당미효낭홍린적첨가질량분수위15％시，PA6／MRP적겁한양지수LOI대우28．2％，이PP／MRP적겁한양지수LOI대우22．4％．
Microencapsulated red phosphorus( MRP) was prepared through inverse suspension poly-merization of melamine and formaldehyde ( MF) on the surface of red phosphorus ( RP) powder, and its structure was characterized by Fourier transform infrared ( FT-IR) spectroscopy, scanning electron mi-croscopy (SEM), and X-ray photoelectron spectroscopy (XPS).The limiting oxygen index (LOI) for MRP composites with polypropylene ( PP) or polyamide 6 ( PA6) was measured.The thermal property of microencapsulated red phosphorus ( MRP) was evaluated and the fire retardant efficiency was tested in PP and PA6 matrix.Experimental results from IR, SEM and XPS confirmed the coating of MF resin onto the surface of RP powder.In the flame retardancy of PA6 and PP, the experimental results showed that the flame retarded PA6 had the LOI>28 .2%when the loading of microencapsulated red phosphorus was 15 wt%, and the flame retarded PP had the LOI >22 .4% when the loading of microencapsulated red phosphorus was 15wt%.