有色金属科学与工程
有色金屬科學與工程
유색금속과학여공정
Nonferrous Metals Science and Engineering
2015年
5期
45-51
,共7页
陈军%梅文捷%曾敏%郭进康%刘德芳%钟盛文
陳軍%梅文捷%曾敏%郭進康%劉德芳%鐘盛文
진군%매문첩%증민%곽진강%류덕방%종성문
有机化合物%羧基酞菁,锂离子电池%正极材料%电化学性能
有機化閤物%羧基酞菁,鋰離子電池%正極材料%電化學性能
유궤화합물%최기태정,리리자전지%정겁재료%전화학성능
organic compound%carboxyl substituted phthalocyanine%lithium ion battery%cathode material%electrochemical performance
采用"固相"模板合成法和特殊的分离提纯工艺制备得到纯净的四羧基取代镍酞菁有机配合物,将其分别与一定比例的导电剂I2混合掺杂,采用球磨分散法制备得到酞菁活性纳米颗粒.以锂片作为负极,考察该纳米活性颗粒的电化学性能,并分析其羧基官能团导电机理.制备的酞菁纳米活性颗粒在0.3~3.2 V截止电压下的初始放电容量为852 mA·h/g,经过20次循环后的放电容量迅速下降到400 mA·h/g左右,此后保持平稳,在第55次循环后的比容量仍然保持300 mA·h/g,初步研究表明具备一定的电化学活性.
採用"固相"模闆閤成法和特殊的分離提純工藝製備得到純淨的四羧基取代鎳酞菁有機配閤物,將其分彆與一定比例的導電劑I2混閤摻雜,採用毬磨分散法製備得到酞菁活性納米顆粒.以鋰片作為負極,攷察該納米活性顆粒的電化學性能,併分析其羧基官能糰導電機理.製備的酞菁納米活性顆粒在0.3~3.2 V截止電壓下的初始放電容量為852 mA·h/g,經過20次循環後的放電容量迅速下降到400 mA·h/g左右,此後保持平穩,在第55次循環後的比容量仍然保持300 mA·h/g,初步研究錶明具備一定的電化學活性.
채용"고상"모판합성법화특수적분리제순공예제비득도순정적사최기취대얼태정유궤배합물,장기분별여일정비례적도전제I2혼합참잡,채용구마분산법제비득도태정활성납미과립.이리편작위부겁,고찰해납미활성과립적전화학성능,병분석기최기관능단도전궤리.제비적태정납미활성과립재0.3~3.2 V절지전압하적초시방전용량위852 mA·h/g,경과20차순배후적방전용량신속하강도400 mA·h/g좌우,차후보지평은,재제55차순배후적비용량잉연보지300 mA·h/g,초보연구표명구비일정적전화학활성.
Pure carboxyl substituted nickel phthalocyanine complexe (Ni-Pc) was obtained using the "solid phase"template synthesis method and special process of separation and purification. The Ni-Pc active material was mixed with iodine and ball milled to obtain the Ni-Pc nanoparticles. The electrochemical performance of the nanoparticles was investigated using lithium plate as counter electrode. The initial discharge capacity of Ni-Pc nanoparticles is 852 mA·h/g in cutoff voltage of 0.3-3.2 V. After 10 cycles,the specific capacity decreases rapidly and reaches a stable value. And the discharge capacity remains at 284 mA ·h/g after 55 times recycling. The primary study indicates that the Ni-Pc nanoparticles compounds show good electrochemical properties.