天津工业大学学报
天津工業大學學報
천진공업대학학보
Journal of Tianjin Polytechnic University
2015年
5期
6-11
,共6页
戴海平%胡宁沙%吴秀丽%柯永文%尹艳梅%迟庆峰%刘建路%潘玉强
戴海平%鬍寧沙%吳秀麗%柯永文%尹豔梅%遲慶峰%劉建路%潘玉彊
대해평%호저사%오수려%가영문%윤염매%지경봉%류건로%반옥강
超滤%高盐卤水%跨膜压差%膜比通量%水处理
超濾%高鹽滷水%跨膜壓差%膜比通量%水處理
초려%고염서수%과막압차%막비통량%수처리
ultrafiltration%high salt brine%transmembrane pressure%membrane specific flux%water treatment
采用“自清洗过滤器+超滤系统”组合技术处理山东海化集团高盐度地下卤水,作为纳滤单元的预处理工艺.采用天津膜天膜科技股份有限公司的外压式中空纤维超滤膜,进行膜通量和清洗频率2种工艺参数的优化,根据实验数据和理论数据分析得到了CEB清洗对膜污染控制效果,并且进行小试,优化了清洗药剂的选择.经过一段时间试运行,结果表明:膜通量为40 L/(m2·h)时为最佳膜运行通量,膜设备在此通量下可以长期稳定运行,并且回收率始终保持95%左右;CEB清洗效果较好;超滤出水未检测出藻类,说明对藻类去除效果较好,超滤出水浊度基本在0.1 NTU以下,出水SDI15小于3,平均出水TOC为11.7 mg/L,满足后续纳滤进水要求.
採用“自清洗過濾器+超濾繫統”組閤技術處理山東海化集糰高鹽度地下滷水,作為納濾單元的預處理工藝.採用天津膜天膜科技股份有限公司的外壓式中空纖維超濾膜,進行膜通量和清洗頻率2種工藝參數的優化,根據實驗數據和理論數據分析得到瞭CEB清洗對膜汙染控製效果,併且進行小試,優化瞭清洗藥劑的選擇.經過一段時間試運行,結果錶明:膜通量為40 L/(m2·h)時為最佳膜運行通量,膜設備在此通量下可以長期穩定運行,併且迴收率始終保持95%左右;CEB清洗效果較好;超濾齣水未檢測齣藻類,說明對藻類去除效果較好,超濾齣水濁度基本在0.1 NTU以下,齣水SDI15小于3,平均齣水TOC為11.7 mg/L,滿足後續納濾進水要求.
채용“자청세과려기+초려계통”조합기술처리산동해화집단고염도지하서수,작위납려단원적예처리공예.채용천진막천막과기고빈유한공사적외압식중공섬유초려막,진행막통량화청세빈솔2충공예삼수적우화,근거실험수거화이론수거분석득도료CEB청세대막오염공제효과,병차진행소시,우화료청세약제적선택.경과일단시간시운행,결과표명:막통량위40 L/(m2·h)시위최가막운행통량,막설비재차통량하가이장기은정운행,병차회수솔시종보지95%좌우;CEB청세효과교호;초려출수미검측출조류,설명대조류거제효과교호,초려출수탁도기본재0.1 NTU이하,출수SDI15소우3,평균출수TOC위11.7 mg/L,만족후속납려진수요구.
"Self-cleaning filter+ultrafiltration system"combination technology as a pretreatment process of nanofiltration units was used to treat high salinity of underground brine from ShanDong Ocean Chemical Group Ltd. The technological parameters of membrane flux, washing frequency are optimized by using external pressure type hollow fiber ultrafiltration membranes from Tianjin Motimo Membrane Technology Co Ltd. The selection of effect of CEB cleaning for controlling the membrane fouling is discussed according to the theoretical and experimental data analysis. The cleaning agent is optimized. The results showed that membrane flux of 40 L/(m2·h) is the best membrane flux, under this flux, the membrane equipment can keep a long-term stable operation and the water recovery rate is stable around 95%;CEB cleaning effect is good, the equipment has a high stability, and recovery rate is stable for a long time. No algae is detected in the UF effluent, which show the combination technology has a good effect on algae removal. The effluent turbidity water was under 0.1 NTU, SDI15 was less than 3, the average effluent TOC was 11.7 mg/L, this satifies the requirements of subsequent nanofiltration into the water.