自然杂志
自然雜誌
자연잡지
Chinese Journal of Nature
2015年
5期
317-324
,共8页
赵静%罗宏杰%王丽琴%李伟东
趙靜%囉宏傑%王麗琴%李偉東
조정%라굉걸%왕려금%리위동
复合盐%NaCl/NaNO3%陶质文物%破坏作用
複閤鹽%NaCl/NaNO3%陶質文物%破壞作用
복합염%NaCl/NaNO3%도질문물%파배작용
composite salt%NaCl/NaNO3%ancient pottery%damage effect
针对目前关于典型可溶盐NaCl、NaNO3和两者的复合盐对陶质文物破坏作用的研究空白,在分析不同可溶盐以及复合盐溶液的表面张力、浓度变化以及平衡结晶相等的基础上,采用超景深显微系统和自动压汞仪等设备研究可溶盐NaCl/NaNO3对模拟陶质样品的破坏过程和方式,结果表明:复合盐的吸水一失水能力远远高于单一的NaCl和NaNO3,其在陶质样品中的溶解一结晶加速,破坏作用高于单一的可溶盐NaNO3;同时,含复合盐陶质样品的呈蘑菇状包裹的盐硬壳层在相对湿度的变化过程中,连续的盐结壳面积逐渐降低,不连续的结壳层面积增多,样品的平均孔径变小,小孔体积含量增加,微小裂缝逐渐扩张。本研究分析复合盐NaCl/NaNO3破坏陶质文物的过程和作用,为酥粉陶质文物的进一步保护研究提供科学依据。
針對目前關于典型可溶鹽NaCl、NaNO3和兩者的複閤鹽對陶質文物破壞作用的研究空白,在分析不同可溶鹽以及複閤鹽溶液的錶麵張力、濃度變化以及平衡結晶相等的基礎上,採用超景深顯微繫統和自動壓汞儀等設備研究可溶鹽NaCl/NaNO3對模擬陶質樣品的破壞過程和方式,結果錶明:複閤鹽的吸水一失水能力遠遠高于單一的NaCl和NaNO3,其在陶質樣品中的溶解一結晶加速,破壞作用高于單一的可溶鹽NaNO3;同時,含複閤鹽陶質樣品的呈蘑菇狀包裹的鹽硬殼層在相對濕度的變化過程中,連續的鹽結殼麵積逐漸降低,不連續的結殼層麵積增多,樣品的平均孔徑變小,小孔體積含量增加,微小裂縫逐漸擴張。本研究分析複閤鹽NaCl/NaNO3破壞陶質文物的過程和作用,為酥粉陶質文物的進一步保護研究提供科學依據。
침대목전관우전형가용염NaCl、NaNO3화량자적복합염대도질문물파배작용적연구공백,재분석불동가용염이급복합염용액적표면장력、농도변화이급평형결정상등적기출상,채용초경심현미계통화자동압홍의등설비연구가용염NaCl/NaNO3대모의도질양품적파배과정화방식,결과표명:복합염적흡수일실수능력원원고우단일적NaCl화NaNO3,기재도질양품중적용해일결정가속,파배작용고우단일적가용염NaNO3;동시,함복합염도질양품적정마고상포과적염경각층재상대습도적변화과정중,련속적염결각면적축점강저,불련속적결각층면적증다,양품적평균공경변소,소공체적함량증가,미소렬봉축점확장。본연구분석복합염NaCl/NaNO3파배도질문물적과정화작용,위소분도질문물적진일보보호연구제공과학의거。
As for similar research had not been reported about the discussion of the soluble salt NaCl, NaNO3 and their composite in effloresces pottery, the analysis of the properties such as surface tension, concentration and equilibrium crystalline phase of salt solution and their composite were studied, as well as the destructive process and effect of the salt for the pottery was discussed with the test methods of digital microscope and automatic mercury porosimetry etc. The results indicated that the ratio of dissolution and crystallization of composite salt NaCl/NaNO3 was accelerated in pottery samples and the damage effect was serious on the condition of the ability of water absorption and desorption in composite salt NaCl/NaNO3 was much higher than that in single NaCl or NaNO3. The mushroom shaped salt crust in composite salt was wrapped in the pottery particles tightly and the area was gradually decreased under the relative humidity cycles, the micro-cracks was expanded expressed in the continuous salt crust area was decreased and the discontinuous area was increased, which showed as the average pore size of the pottery sample was decreased and the contents of microporous was increased. In all, the process and the action of composite salt NaCl/NaNO3 for the pottery samples were studied for the sake of scientific research in next protection.