CAJ | 학술논문

以钨酸钠为前驱体，通过水热自组装合成钨酸纳米片，再将其在氢气/甲烷混合气氛中还原碳化获得碳化钨纳米片。采用场发射扫描电子显微镜、X射线衍射、透射电子显微镜和氮吸附等手段对样品形貌、晶相、微结构和比表面积进行分析与表征；采用粉末微电极和循环伏安法测试样品的电催化性能。结果表明：样品颗粒为方形片状，长和宽为600~800 nm，厚约90 nm；样品由碳化钨和碳化二钨组成；纳米片由纳米颗粒和孔隙构成；样品的比表面积为31 m2/g，平均孔径为3.5 nm；碳化钨纳米片呈介孔结构，碳化钨纳米片对甲醇电催化氧化具有良好的活性，并具有与铂类似的催化性能。
이오산납위전구체，통과수열자조장합성오산납미편，재장기재경기/갑완혼합기분중환원탄화획득탄화오납미편。채용장발사소묘전자현미경、X사선연사、투사전자현미경화담흡부등수단대양품형모、정상、미결구화비표면적진행분석여표정；채용분말미전겁화순배복안법측시양품적전최화성능。결과표명：양품과립위방형편상，장화관위600~800 nm，후약90 nm；양품유탄화오화탄화이오조성；납미편유납미과립화공극구성；양품적비표면적위31 m2/g，평균공경위3.5 nm；탄화오납미편정개공결구，탄화오납미편대갑순전최화양화구유량호적활성，병구유여박유사적최화성능。
Tungsten trioxide nanoplate was prepared by hydrothermal self-assembling method using sodium tungstate as precursor, then the nanoplate was reduced and carbonized under H 2 and CH 4 atmosphere to get tungsten carbide nanoplate. The morphology, crystal phase, microstructure and specific area of the samples were characterized by scanning electron microscopy, X-ray diffractometry, transmission electron microscopy and Brunauer–Emmett–Teller surface tester. The electrocatalytic property of the nanoplate was measured through power microelectrode approach with cyclic voltammetry using a three-electrode system in acidic aqueous solution. The results show that the morphology of the sample is regular square plate, with length and width of 600?800 nm and thickness of around 90 nm, respectively;the crystal phase of the sample is composed of monotungsten carbide and bitungsten carbide; the nanoplate constitutes of nanoparticles and pores;the specific area of the sample is 31 m2/g, and the average diameter of the pore is around 3.5 nm. The nanoplate with mesoporosity is active to methanol electrocatalytic oxidation, and its electrocatalytic property is similar to that of platinum.