化工进展
化工進展
화공진전
Chemical Industry and Engineering Progress
2015年
11期
4065-4070
,共6页
罗曼%蔡旺锋%陈益清%张旭斌
囉曼%蔡旺鋒%陳益清%張旭斌
라만%채왕봉%진익청%장욱빈
磁加载絮凝%含铜废水%粒度分布%沉降%分离
磁加載絮凝%含銅廢水%粒度分佈%沉降%分離
자가재서응%함동폐수%립도분포%침강%분리
magnetic seedingflocculation%copper waste water%particle size distribution%sedimentation%separation
目前磁加载絮凝技术已被研究用于处理多种类型的废水,然而关于此技术中磁粉作用机理方向少有报道。为了解决这一问题,本文采用磁加载絮凝法处理模拟微蚀铜废水,研究了磁粉的加入对 Cu2+和浊度去除率、絮体沉降速率以及絮体粒径的影响,深入分析了磁粉的作用规律和机理,为磁加载絮凝法应用到实际工程中提供了理论依据和技术参数。结果表明,当磁粉投加量和粒径分别取2.0g/L和300~400目时,磁加载絮凝效果最好。此时,Cu2+和浊度去除率均达到最高值98.53%和94.72%,比传统絮凝法高出4.11%和0.61%;絮体沉降速率最快,达5cm/min,是传统絮凝沉降速率的3.64倍;絮体粒径D50也达到最大值41.94μm,较传统絮体粒径大20μm。磁粉投加量过多或过少、粒径过大或过小都会相应地减慢磁絮体的生长速率。
目前磁加載絮凝技術已被研究用于處理多種類型的廢水,然而關于此技術中磁粉作用機理方嚮少有報道。為瞭解決這一問題,本文採用磁加載絮凝法處理模擬微蝕銅廢水,研究瞭磁粉的加入對 Cu2+和濁度去除率、絮體沉降速率以及絮體粒徑的影響,深入分析瞭磁粉的作用規律和機理,為磁加載絮凝法應用到實際工程中提供瞭理論依據和技術參數。結果錶明,噹磁粉投加量和粒徑分彆取2.0g/L和300~400目時,磁加載絮凝效果最好。此時,Cu2+和濁度去除率均達到最高值98.53%和94.72%,比傳統絮凝法高齣4.11%和0.61%;絮體沉降速率最快,達5cm/min,是傳統絮凝沉降速率的3.64倍;絮體粒徑D50也達到最大值41.94μm,較傳統絮體粒徑大20μm。磁粉投加量過多或過少、粒徑過大或過小都會相應地減慢磁絮體的生長速率。
목전자가재서응기술이피연구용우처리다충류형적폐수,연이관우차기술중자분작용궤리방향소유보도。위료해결저일문제,본문채용자가재서응법처리모의미식동폐수,연구료자분적가입대 Cu2+화탁도거제솔、서체침강속솔이급서체립경적영향,심입분석료자분적작용규률화궤리,위자가재서응법응용도실제공정중제공료이론의거화기술삼수。결과표명,당자분투가량화립경분별취2.0g/L화300~400목시,자가재서응효과최호。차시,Cu2+화탁도거제솔균체도최고치98.53%화94.72%,비전통서응법고출4.11%화0.61%;서체침강속솔최쾌,체5cm/min,시전통서응침강속솔적3.64배;서체립경D50야체도최대치41.94μm,교전통서체립경대20μm。자분투가량과다혹과소、립경과대혹과소도회상응지감만자서체적생장속솔。
Magnetic seeding flocculation(hereinafter referred to as MSF) has been studied and applied to various types of waste water treatment,but very few studies have been reported regarding magnetic seed mechanism. In order to solve this problem,MSF method was conducted in this study to simulate micro-etching copper waste water. This study compared the influences of dosing magnetic seed on removal rates of copper and turbidity,floc sedimentation rate or floc size,and analyzed the mechanism of magnetic seed effectiveness. The results showed that MSF reached its best performance at 2.0g/L and particle sizes between 300 and 400 mesh. Under optimal conditions,the highest removal rates for copper and turbidity were 98.53% and 94.72%,4.11% and 0.61% higher than traditional flocculation respectively; settling speed also reached its maximum of 5cm/min,2.64 times greater than traditional flocculation;and floc sizeD50 also reached its maximum of 41.94μm,20 micrometers larger than traditional particle size. The above figures indicated that the floc growth rate was affected by magnetic seed dosage and particle size. This study provided theoretical and practical parameters for the application of MSF.