化工技术与开发
化工技術與開髮
화공기술여개발
Technology & Development of Chemical Industry
2015年
10期
17-19
,共3页
氯代环己烷%合成新工艺%精馏
氯代環己烷%閤成新工藝%精餾
록대배기완%합성신공예%정류
chloroxyclohexene%new synthesis process%distillation
研究了以苯为原料，部分加氢制备环己烯，产物环己烯、环己烷和未反应的苯不经分离，直接与氯化氢加成制备氯代环己烷的合成新工艺路线。该工艺解决了沸点相近的苯、环己烷、环己烯难以分离的问题，氯代环己烷在产物中采用普通精馏分离。考察了进料组成、进料量、进料热状况对氯代环己烷精馏产品质量的影响，结果显示，氯代环己烷产品常压精馏的最佳工艺实验条件为：加热电压200V,全回流70min,变回流比1.5~3.5。
研究瞭以苯為原料，部分加氫製備環己烯，產物環己烯、環己烷和未反應的苯不經分離，直接與氯化氫加成製備氯代環己烷的閤成新工藝路線。該工藝解決瞭沸點相近的苯、環己烷、環己烯難以分離的問題，氯代環己烷在產物中採用普通精餾分離。攷察瞭進料組成、進料量、進料熱狀況對氯代環己烷精餾產品質量的影響，結果顯示，氯代環己烷產品常壓精餾的最佳工藝實驗條件為：加熱電壓200V,全迴流70min,變迴流比1.5~3.5。
연구료이분위원료，부분가경제비배기희，산물배기희、배기완화미반응적분불경분리，직접여록화경가성제비록대배기완적합성신공예로선。해공예해결료비점상근적분、배기완、배기희난이분리적문제，록대배기완재산물중채용보통정류분리。고찰료진료조성、진료량、진료열상황대록대배기완정류산품질량적영향，결과현시，록대배기완산품상압정류적최가공예실험조건위：가열전압200V,전회류70min,변회류비1.5~3.5。
In this paper,a new synthesis process of chloroxyclohexene was reported which benzene partically hydrogenated to make cyclohexene and then reacted with hydrogen chloride. The process solved the problem of similar boiling point difficult to separate of benzene and cyclohexene and cyclohexane. Chloroxyclohexene was separated easily which used nomal purification. Influnce factors of rectify were studied which included feed composition, feed rate, the inlet hot condition,etc. The optimal operation conditions of chloroxyclohexene nomal pressure distillation were as followed:the heating voltage was 200V, total reflux time was 70min, and the reflux ratio was 1.5~3.5.
