CAJ | 학술논문

基于煤焦油组成的复杂性以及含硫化合物的同分异构体数量较多，今提出了一套含硫化合物形态分析方法。采用溶剂萃取法与柱层析法相结合对某煤气厂煤焦油进行了族组分分离，并利用气质联用仪(GC-MS)分析了芳香分与极性物的组成，同时采用GC-AED与GC-MS联合定性方法对芳香分和极性物中的含硫化合物进行了形态分析，采用XPS对甲苯不溶物中的硫化物进行了定性分析。结果表明，在芳香分组分中，GC-MS共检测到102种化合物，GC-AED共检测并定性了40种含硫化合物；在极性物组分中，GC-MS共检测到69种化合物，GC-AED定性了30种含硫化合物，甲苯不溶物中的含硫化合物主要为噻吩类、R-O-S-S-R 等硫氧化物以及砜类。该方法可用于分析其它煤基液体产品的组成以及含硫化合物形态分布。
기우매초유조성적복잡성이급함류화합물적동분이구체수량교다，금제출료일투함류화합물형태분석방법。채용용제췌취법여주층석법상결합대모매기엄매초유진행료족조분분리，병이용기질련용의(GC-MS)분석료방향분여겁성물적조성，동시채용GC-AED여GC-MS연합정성방법대방향분화겁성물중적함류화합물진행료형태분석，채용XPS대갑분불용물중적류화물진행료정성분석。결과표명，재방향분조분중，GC-MS공검측도102충화합물，GC-AED공검측병정성료40충함류화합물；재겁성물조분중，GC-MS공검측도69충화합물，GC-AED정성료30충함류화합물，갑분불용물중적함류화합물주요위새분류、R-O-S-S-R 등류양화물이급풍류。해방법가용우분석기타매기액체산품적조성이급함류화합물형태분포。
Coal tar is a complex mixture and the sulfuric compounds within coal tar have many isomers. An analysis method for the study of sulfuric compound in coal tar was proposed in this study. The coae tar was separated into groups using solvent extraction and column chromatography. GC-MS was used to analyze the compositions of the aromatic and polar fraction. The sulfuric compounds in the aromatic and polar fractions were analyzed by GC-AED and GC-MS, and the sulfuric compounds in toluene insoluble fractions were analyzed by XPS. The results show that 102 compounds were detected by GC-MS in the aromatic fraction and 40 sulfur compounds were identified by GC-AED, while 69 compounds were detected by GC-MS and 30 sulfuric compounds were identified by GC-AED in the polar fraction. The sulfuric compounds in the toluene insoluble fractions are mainly thiophenes, sulfoxides such as R-O-S-S-R, and sulfones. This method can be used to analyze composition and distribution of sulfuric compounds in other coal-derived oil products.