粮食与油脂
糧食與油脂
양식여유지
Cereals & Oils
2015年
10期
50-53
,共4页
胆碱类离子液体%催化%麻疯树果油%酯交换%生物柴油
膽堿類離子液體%催化%痳瘋樹果油%酯交換%生物柴油
담감류리자액체%최화%마풍수과유%지교환%생물시유
choline ionic liquids%catalytic%Jatrophacurcasoil%transesterification%biodiesel
采用两步法合成了咪唑阴离子型碱性胆碱类离子液体ChIm，以麻疯树果油为原料，考察了其对麻疯树果油和甲醇酯交换制备生物柴油的催化性能。通过单因素实验，考察了反应温度、反应时间、催化剂用量和醇油摩尔比对生物柴油产率的影响。研究表明，当反应温度T=65℃，反应时间t=3 h，催化剂用量为4%，醇油摩尔比为6∶1时，生物柴油产率可达94.7%，且离子液体易于分离回收，重复使用性能较好。
採用兩步法閤成瞭咪唑陰離子型堿性膽堿類離子液體ChIm，以痳瘋樹果油為原料，攷察瞭其對痳瘋樹果油和甲醇酯交換製備生物柴油的催化性能。通過單因素實驗，攷察瞭反應溫度、反應時間、催化劑用量和醇油摩爾比對生物柴油產率的影響。研究錶明，噹反應溫度T=65℃，反應時間t=3 h，催化劑用量為4%，醇油摩爾比為6∶1時，生物柴油產率可達94.7%，且離子液體易于分離迴收，重複使用性能較好。
채용량보법합성료미서음리자형감성담감류리자액체ChIm，이마풍수과유위원료，고찰료기대마풍수과유화갑순지교환제비생물시유적최화성능。통과단인소실험，고찰료반응온도、반응시간、최화제용량화순유마이비대생물시유산솔적영향。연구표명，당반응온도T=65℃，반응시간t=3 h，최화제용량위4%，순유마이비위6∶1시，생물시유산솔가체94.7%，차리자액체역우분리회수，중복사용성능교호。
A new basiccholine ionic liquids ChIm with an imidazolide anion group was synthesized by a two-stepmethod. Itscatalytic activity in the transesterificationof Jatrophacurcasoil withmethanol to produce biodiesel was investigated.The effectsof reaction temperature,reaction time,catalyst concentration and themolar ratioofmethanol to Jatrophacurcasoilon the yieldof biodiesel were investigated.The results indicated that the yieldof biodieselcould reach 94.7% under theconditions ofT=65℃,t=3h,catalystconcentration 4%,themolar ratioofmethanol to Jatrophacurcasoil 6∶1, moreover,itcould be easily separated from the reaction system as well as repeatedly used.
