化工进展
化工進展
화공진전
Chemical Industry and Engineering Progress
2015年
z1期
60-65
,共6页
甲烷%重整%积炭%热力学%燃料电池
甲烷%重整%積炭%熱力學%燃料電池
갑완%중정%적탄%열역학%연료전지
methane%reforming%carbon deposition%thermodynamics%fuel cell
从热力学的角度对甲烷重整过程中的积炭现象进行了综述研究，分析了 C-H-O 三元素组分的积炭三角图以及不同甲烷重整形式的非积炭区域，包括了 SMR、CDR、POM、TRM以及甲烷在燃料电池电化学阳极室中的重整过程。最后提出了热力学视角下缓解积炭的措施是联合重整能有效地减少积炭，而采用阳极注氧能够改善甲烷燃料电池的积炭现象。
從熱力學的角度對甲烷重整過程中的積炭現象進行瞭綜述研究，分析瞭 C-H-O 三元素組分的積炭三角圖以及不同甲烷重整形式的非積炭區域，包括瞭 SMR、CDR、POM、TRM以及甲烷在燃料電池電化學暘極室中的重整過程。最後提齣瞭熱力學視角下緩解積炭的措施是聯閤重整能有效地減少積炭，而採用暘極註氧能夠改善甲烷燃料電池的積炭現象。
종열역학적각도대갑완중정과정중적적탄현상진행료종술연구，분석료 C-H-O 삼원소조분적적탄삼각도이급불동갑완중정형식적비적탄구역，포괄료 SMR、CDR、POM、TRM이급갑완재연료전지전화학양겁실중적중정과정。최후제출료열역학시각하완해적탄적조시시연합중정능유효지감소적탄，이채용양겁주양능구개선갑완연료전지적적탄현상。
From the perspective of thermodynamics, the carbon deposition phenomenon in methane reforming process were reviewed.The three-element composition of C-H-O triangular diagrams were analyzed,as well as various reforming forms of non-carbon deposition region, including the SMR,CDR,POM,TRM,and methane reforming process in the anode of fuel cell.Finally, the mitigate carbon deposition measures were proposed at thermodynamic perspective:the combined reforming forms can minimizes carbon deposition,while the use of anodic oxygen inj ection, the carbon deposition of methane reforming in fuel cells can be improved.
