CAJ | 학술논문

介绍了Ni2 P催化剂的结构特征、加氢脱氧（HDO ）活性相及生物油中典型的含氧化合物，综述了具有代表性的典型含氧化合物呋喃类、酚类、醚类和酯类在Ni2 P催化剂催化下的 HDO机理方面的最新研究进展。 HDO过程中，含氧化合物在催化剂作用下发生C—O键断裂， O主要通过加氢‐氢解以 H2 O的形式脱除，其脱氧产物较为复杂。生物油中富含呋喃类和酚类化合物，因需要苛刻的脱氧反应条件，它们的脱氧难度最大。今后，需进一步深入开展HDO理论研究，探究Ni2 P催化剂催化活性的调控机制，制备出性能更加优异的 HDO催化剂。
개소료Ni2 P최화제적결구특정、가경탈양（HDO ）활성상급생물유중전형적함양화합물，종술료구유대표성적전형함양화합물부남류、분류、미류화지류재Ni2 P최화제최화하적 HDO궤리방면적최신연구진전。 HDO과정중，함양화합물재최화제작용하발생C—O건단렬， O주요통과가경‐경해이 H2 O적형식탈제，기탈양산물교위복잡。생물유중부함부남류화분류화합물，인수요가각적탈양반응조건，타문적탈양난도최대。금후，수진일보심입개전HDO이론연구，탐구Ni2 P최화제최화활성적조공궤제，제비출성능경가우이적 HDO최화제。
T he structure and the active phase for hydrodeoxygenation (HDO ) of Ni2 P catalyst and the typical oxygen‐containing compounds in bio‐oil were introduced . The recent progress in the HDO mechanism over Ni2 P catalysts based on representative oxygen‐containing compounds ,such as furans ,phenols ,ethers and esters ,was reviewed .During HDO ,C—O bonds of oxygen‐containing compounds were cleaved under the action of catalysts ,and then the oxygen was mainly removed by hydrogenation‐hydrogenolysis in the form of H2O ,by which complicated products were produced . Bio‐oils were rich in furans and phenolic compounds ,and the deoxidization of these compounds needed harsh reaction conditions ,therefore ,their HDO were of the most challenging .To prepare the catalysts with more excellent HDO performance ,the HDO theoretical research and regulatory mechanism for HDO activity of the Ni2 P catalyst were worthy of being further studied .