CAJ | 학술논문

按照文献方法，制备了2，6-二氨基-3，5-二硝基吡啶-1-氧化物（ANPyO）Ni（II）和 Cu（II）两种含能配合物，用激光粒度测试仪及 GJB772A-97法测试了粒度和感度，用密闭爆发器分别测试了含 ANPyO Ni（II）和 Cu（II）配合物发射药的燃烧性能，用靶线法测试了含两种配合物双基推进剂的燃烧催化性能。研究了两种配合物在双基发射药、三基发射药和双基推进剂中的燃烧作用。结果表明，ANPyO Ni（II）和 Cu（II）两种配合物粒度都为微米级，爆速大于8200 m／s，爆压大于32 GPa，优于 TATB、HNS 和 PYX；两种含能配合物能够提高双基发射药的燃速，使其压强指数分别降低7．61％和3．29％，对双基发射药的燃烧性能具有明显的促进效果；ANPyO Cu（II）配合物使双基推进剂在10～20 MPa 下燃速提高20％，压强指数降低17．78％～55．84％，对双基推进剂的燃烧性能具有良好的催化效果。
안조문헌방법，제비료2，6-이안기-3，5-이초기필정-1-양화물（ANPyO）Ni（II）화 Cu（II）량충함능배합물，용격광립도측시의급 GJB772A-97법측시료립도화감도，용밀폐폭발기분별측시료함 ANPyO Ni（II）화 Cu（II）배합물발사약적연소성능，용파선법측시료함량충배합물쌍기추진제적연소최화성능。연구료량충배합물재쌍기발사약、삼기발사약화쌍기추진제중적연소작용。결과표명，ANPyO Ni（II）화 Cu（II）량충배합물립도도위미미급，폭속대우8200 m／s，폭압대우32 GPa，우우 TATB、HNS 화 PYX；량충함능배합물능구제고쌍기발사약적연속，사기압강지수분별강저7．61％화3．29％，대쌍기발사약적연소성능구유명현적촉진효과；ANPyO Cu（II）배합물사쌍기추진제재10～20 MPa 하연속제고20％，압강지수강저17．78％～55．84％，대쌍기추진제적연소성능구유량호적최화효과。
Two energetic Ni(II)and Cu(II)complexes of 2,6-diamino-3,5-dinitropyridine-1-oxide (ANPyO)were synthesized according to the method of literature.The particle size and detonation performance were tested by laser particle size analyzer and GJB772A-97 method.Combustion properties of gun propellants and propellants with AN-PyO Ni(II)and Cu(II)complexes were tested using the closed bomb test and target line method,respectively.The combustion catalysis of two complexes in double-base gun propellants,triple-base gun propellants and double-base propellants were studied.Results show that the particle sizes of two complexes are micron level and their detonation velocities are more than 8 200 m/s and detonation pressures are greater than 32 GPa ,which are better than those of TATB、HNS and PYX.The Ni(II)complex and Cu(II)complex have evident catalytic effects on the combustion of double-base gun propellants and make the burning rate of two kinds of energetic complexes increase and the pressure exponent decrease by 7.61 % and 3.29%,respectively.The Cu(II)complex has significant effects on the combustion of double-base propellants,which makes the burning rate increase by 20% and the pressure exponent decrease by 17.78%-55.84% in the pressure range of 10-20 MPa.