天津科技
天津科技
천진과기
Tianjin Science & Technology
2015年
10期
20-23
,共4页
羰基合成%催化剂母液%化学再生%活性
羰基閤成%催化劑母液%化學再生%活性
탄기합성%최화제모액%화학재생%활성
oxo synthesis%mother liquid of catalyst%chemical regeneration%activity
通过对丁辛醇羰基合成反应的催化剂的研究,指出了适合的丁辛醇1#装置催化剂母液化学再生的工艺路线。经过实验优化,最终催化剂活性由26%,提高到59%,,催化反应温度也从94,℃降低到88,℃,合成气和丙烯的消耗降低,生产运行负荷可以提高到100%,,对生产的稳定操作、节能减排、降低消耗起到了关键作用;同时能够延长催化剂的使用寿命,降低生产成本,提高经济效益。
通過對丁辛醇羰基閤成反應的催化劑的研究,指齣瞭適閤的丁辛醇1#裝置催化劑母液化學再生的工藝路線。經過實驗優化,最終催化劑活性由26%,提高到59%,,催化反應溫度也從94,℃降低到88,℃,閤成氣和丙烯的消耗降低,生產運行負荷可以提高到100%,,對生產的穩定操作、節能減排、降低消耗起到瞭關鍵作用;同時能夠延長催化劑的使用壽命,降低生產成本,提高經濟效益。
통과대정신순탄기합성반응적최화제적연구,지출료괄합적정신순1#장치최화제모액화학재생적공예로선。경과실험우화,최종최화제활성유26%,제고도59%,,최화반응온도야종94,℃강저도88,℃,합성기화병희적소모강저,생산운행부하가이제고도100%,,대생산적은정조작、절능감배、강저소모기도료관건작용;동시능구연장최화제적사용수명,강저생산성본,제고경제효익。
Through the study of catalysts for butyl octyl alcohol carbonyl synthesis,the suitable chemical regeneration process route for mother liquid of 1# unit catalyst was presented.Via experimental optimization,final catalyst activity increased from 26%to 59%,catalytic reaction temperature reduced from 94,℃to 88,℃.Meanwhile,the syngas and pro-pylene consumption was reduced and the operation load increased to 100%,which plays a key role in the stable operation, energy conservation and emissions reduction.The route also prolongs the service life of catalyst,reduces production cost and improves economic returns.