化工时刊
化工時刊
화공시간
Chemical Industry Times
2015年
9期
9-13
,共5页
孙绍晖%马春松%孙培勤%陈俊武
孫紹暉%馬春鬆%孫培勤%陳俊武
손소휘%마춘송%손배근%진준무
糠醛%糠醇%催化加氢
糠醛%糠醇%催化加氫
강철%강순%최화가경
furfural%furfuryl alcohol%Catalytic hydrogenation
本文主要介绍了间歇式反应釜中糠醛在Cu-Zn/γAl2 O3催化剂条件下在不同温度、时间、糠醛浓度和溶剂体系中的催化加氢制糠醇,从糠醛转化率和糠醇选择性两方面对加氢效果进行比较。通过实验,我们得到了糠醛加氢制糠醇的最佳工艺条件为反应温度为160℃、反应时间为3 h、催化剂用量为糠醛的7wt%、糠醛浓度为5wt%~25wt%、溶剂为甲苯时,糠醛的转化率和糠醇的选择性最好,分别为99%和98%。
本文主要介紹瞭間歇式反應釜中糠醛在Cu-Zn/γAl2 O3催化劑條件下在不同溫度、時間、糠醛濃度和溶劑體繫中的催化加氫製糠醇,從糠醛轉化率和糠醇選擇性兩方麵對加氫效果進行比較。通過實驗,我們得到瞭糠醛加氫製糠醇的最佳工藝條件為反應溫度為160℃、反應時間為3 h、催化劑用量為糠醛的7wt%、糠醛濃度為5wt%~25wt%、溶劑為甲苯時,糠醛的轉化率和糠醇的選擇性最好,分彆為99%和98%。
본문주요개소료간헐식반응부중강철재Cu-Zn/γAl2 O3최화제조건하재불동온도、시간、강철농도화용제체계중적최화가경제강순,종강철전화솔화강순선택성량방면대가경효과진행비교。통과실험,아문득도료강철가경제강순적최가공예조건위반응온도위160℃、반응시간위3 h、최화제용량위강철적7wt%、강철농도위5wt%~25wt%、용제위갑분시,강철적전화솔화강순적선택성최호,분별위99%화98%。
Using Cu-Zn/γAl2 O3 as catalyst, the catalytic hydrogenation of furfural to furfuryl alcohol was de-scribed at different temperatures, time, furfural concentration and solvent system. The different hydrogenation effects were compared at furfural conversion and furfuryl alcohol selectivity. Through experiments, the optimum conditions were determined for hydrogenation of furfural as a reaction temperature of 160 ℃, reaction time 3h, the amount of catalyst is furfural 7wt%, furfural concentration of 5wt% ~25wt%. When the solvent was toluene, the furfural con-version and furfuryl alcohol selectivity were respectively up to99% and 98%.