林产化学与工业
林產化學與工業
림산화학여공업
Chemistry and Industry of Forest Products
2015年
5期
149-158
,共10页
郑云武%杨晓琴%王霏%刘灿%郑志锋%顾继友
鄭雲武%楊曉琴%王霏%劉燦%鄭誌鋒%顧繼友
정운무%양효금%왕비%류찬%정지봉%고계우
选择性催化裂解%沸石微孔分子筛%介孔分子筛%浸渍改性%芳烃化合物
選擇性催化裂解%沸石微孔分子篩%介孔分子篩%浸漬改性%芳烴化閤物
선택성최화렬해%비석미공분자사%개공분자사%침지개성%방경화합물
selective catalytic pyrolysis%zeolite microporous molecular sieve%mesoporous molecular sieve%impregnation modification%aromatic hydrocarbons
鉴于芳烃化合物重要的应用价值以及广阔的市场前景,详细阐述了生物质为原料催化转化制备高附加值芳烃化合物的研究进展,系统概述了生物质原料的种类、模型化合物的种类、沸石分子筛催化剂、介孔分子筛催化剂、催化剂的浸渍改性以及工艺条件等对生物质催化转化制备芳烃化合物的影响,进而探讨了催化热解机理,为生物质的全组分、高资源化利用提供新的方向。
鑒于芳烴化閤物重要的應用價值以及廣闊的市場前景,詳細闡述瞭生物質為原料催化轉化製備高附加值芳烴化閤物的研究進展,繫統概述瞭生物質原料的種類、模型化閤物的種類、沸石分子篩催化劑、介孔分子篩催化劑、催化劑的浸漬改性以及工藝條件等對生物質催化轉化製備芳烴化閤物的影響,進而探討瞭催化熱解機理,為生物質的全組分、高資源化利用提供新的方嚮。
감우방경화합물중요적응용개치이급엄활적시장전경,상세천술료생물질위원료최화전화제비고부가치방경화합물적연구진전,계통개술료생물질원료적충류、모형화합물적충류、비석분자사최화제、개공분자사최화제、최화제적침지개성이급공예조건등대생물질최화전화제비방경화합물적영향,진이탐토료최화열해궤리,위생물질적전조분、고자원화이용제공신적방향。
Due to the important application value and broad market prospect of aromatic hydrocarbons , the research progress on the production of aromatics from catalytic conversion of biomass was reviewed. The effects of feedstock, model compound, zeolite microporous molecular sieve catalyst, mesoporous molecular sieve catalyst and impregnation modification of catalyst as well as reaction condition on reaction selectivity and yield for the formation of aromatics hydrocarbons were summarized in detail. The reaction mechanism were further discussed. This review might provide a new direction for the total components and high value utilization of biomass.