CAJ | 학술논문

先采用固相法制备Sn0.95 Ta0.05 P2 O7电解质样品，再与适量聚四氟乙烯( PTFE)进行复合合成了有机-无机复合电解质聚四氟乙烯/Sn0.95 Ta0.05 P2 O7。 XRD测试表明PTFE/Sn0.95 Ta0.05 P2 O7复合电解质衍射图谱与焦磷酸锡的JCPDS标准衍射图谱卡立方相SnP2O7(JCPDS 00-029-1352)相同，还可以看出复合后新增加了PTFE的衍射峰，表明Sn0.95Ta0.05P2O7和PTFE复合没有发生反应生成新物质。 SEM图可以看出样品致密性良好。采用电化学工作站对样品的中温电性能(40~200℃)进行了研究。结果表明， Sn0.95Ta0.05P2O7/PTFE在160℃下，电导率达到最大值为：1.7×10-2 S·cm-1。
선채용고상법제비Sn0.95 Ta0.05 P2 O7전해질양품，재여괄량취사불을희( PTFE)진행복합합성료유궤-무궤복합전해질취사불을희/Sn0.95 Ta0.05 P2 O7。 XRD측시표명PTFE/Sn0.95 Ta0.05 P2 O7복합전해질연사도보여초린산석적JCPDS표준연사도보잡립방상SnP2O7(JCPDS 00-029-1352)상동，환가이간출복합후신증가료PTFE적연사봉，표명Sn0.95Ta0.05P2O7화PTFE복합몰유발생반응생성신물질。 SEM도가이간출양품치밀성량호。채용전화학공작참대양품적중온전성능(40~200℃)진행료연구。결과표명， Sn0.95Ta0.05P2O7/PTFE재160℃하，전도솔체도최대치위：1.7×10-2 S·cm-1。
The Sn0. 95 Ta0. 05 P2 O7 was obtained by a solid-state reaction method. The calculated amount of PTFE was mixed with Sn0. 95 Ta0. 05 P2 O7 according to proper weight ratio to produce new organic-inorganic composite electrolyte Sn0. 95 Ta0. 05 P2 O7/PTFE. XRD showed that the PTFE/Sn0. 95 Ta0. 05 P2 O7 showed a single cubic phase structure in agreement with that of SnP2 O7 in JCPDS ( 00-029-1352 ) , besides, there was an additional peak of polytetrafluoroethylene ( PTFE ) , there were only peaks corresponding well to Sn0. 95 Ta0. 05 P2 O7 and PTFE, without any formation of other substances. SEM images showed that composite electrolyte was sufficiently dense. The intermediate temperature conduction behavior was investigated by AC impedance spectroscopy in the range of 40~200℃. The highest conductivity was observed to be 1. 7 × 10-2 S·cm-1 for Sn0. 95 Ta0. 05 P2 O7/PTFE at 160 ℃.