安徽理工大学学报(自然科学版)
安徽理工大學學報(自然科學版)
안휘리공대학학보(자연과학판)
Journal of Anhui University of Science and Technology (Natural Science)
2015年
3期
14-16,20
,共4页
炼焦煤%有机硫%XPS
煉焦煤%有機硫%XPS
련초매%유궤류%XPS
coking coal%organic sulfur%XPS
基于煤密度特性的差异,探讨煤中主要有害元素硫的结构和赋存形态,有利于煤精细加工新技术的开发。采用XPS分析方法研究我国炼焦煤主产地山西不同密度煤样中有机硫的赋存形态及相对含量。结果显示,煤样中有机硫形态主要有硫醇(醚)、噻吩、(亚)砜三类,有机硫形态随煤密度不发生变化,噻吩硫相对含量随煤密度增大而降低,其它两类有机硫总量随煤密度增大而升高。
基于煤密度特性的差異,探討煤中主要有害元素硫的結構和賦存形態,有利于煤精細加工新技術的開髮。採用XPS分析方法研究我國煉焦煤主產地山西不同密度煤樣中有機硫的賦存形態及相對含量。結果顯示,煤樣中有機硫形態主要有硫醇(醚)、噻吩、(亞)砜三類,有機硫形態隨煤密度不髮生變化,噻吩硫相對含量隨煤密度增大而降低,其它兩類有機硫總量隨煤密度增大而升高。
기우매밀도특성적차이,탐토매중주요유해원소류적결구화부존형태,유리우매정세가공신기술적개발。채용XPS분석방법연구아국련초매주산지산서불동밀도매양중유궤류적부존형태급상대함량。결과현시,매양중유궤류형태주요유류순(미)、새분、(아)풍삼류,유궤류형태수매밀도불발생변화,새분류상대함량수매밀도증대이강저,기타량류유궤류총량수매밀도증대이승고。
The structure and occurrence of sulfur in coal of different density were discussed , and the study is ad-vantageous to development of new technology for coal fine processing .The occurrence and relative contents of or-ganic sulfur in different density coal samples from Shanxi Province , where is the major site of coking coal produc-tion, were studied by XPS analysis .The results showed that the main organic sulfur occurrences in the coal sam-ples are mercaptan (ether), thiophene, (sulfoxide), and organic sulfur occurrences do not change with the coal density changes , and the relative content of thiophene sulfur increases or reduces with the coal density changes , total organic sulfur of the other two kinds increases with the coal density rise .