光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
Spectroscopy and Spectral Analysis
2015年
9期
2444-2449
,共6页
肖元芳%何妙洪%张书迪%杭纬
肖元芳%何妙洪%張書迪%杭緯
초원방%하묘홍%장서적%항위
耀州窑%激光电离质谱%着色元素%呈色机理
耀州窯%激光電離質譜%著色元素%呈色機理
요주요%격광전리질보%착색원소%정색궤리
Yaozhou kiln%Laser ionization mass spectrometry%Coloring elements%Colorative mechanism
采用实验室自制飞秒激光电离飞行时间质谱（fs-LI-TOFMS）对唐代、五代、宋代、金代以及明代等五个朝代的耀州窑古瓷片釉层进行多元素同时分析，研究其呈色机理，以过渡元素为重点考察陶瓷釉层中所有可能着色元素的着色效果。推测耀州黑瓷烧制采用的很可能是 Co-Cr-Fe-Mn 系黑色釉料；明代白釉形成的主要原因是 Fe 元素含量低，还有可能与 Ni 元素有关；釉层中 P 元素含量增多会导致釉色偏黄。毫无疑问，这一系列发现是对整个耀州瓷体系釉层呈色机理的重要补充。
採用實驗室自製飛秒激光電離飛行時間質譜（fs-LI-TOFMS）對唐代、五代、宋代、金代以及明代等五箇朝代的耀州窯古瓷片釉層進行多元素同時分析，研究其呈色機理，以過渡元素為重點攷察陶瓷釉層中所有可能著色元素的著色效果。推測耀州黑瓷燒製採用的很可能是 Co-Cr-Fe-Mn 繫黑色釉料；明代白釉形成的主要原因是 Fe 元素含量低，還有可能與 Ni 元素有關；釉層中 P 元素含量增多會導緻釉色偏黃。毫無疑問，這一繫列髮現是對整箇耀州瓷體繫釉層呈色機理的重要補充。
채용실험실자제비초격광전리비행시간질보（fs-LI-TOFMS）대당대、오대、송대、금대이급명대등오개조대적요주요고자편유층진행다원소동시분석，연구기정색궤리，이과도원소위중점고찰도자유층중소유가능착색원소적착색효과。추측요주흑자소제채용적흔가능시 Co-Cr-Fe-Mn 계흑색유료；명대백유형성적주요원인시 Fe 원소함량저，환유가능여 Ni 원소유관；유층중 P 원소함량증다회도치유색편황。호무의문，저일계렬발현시대정개요주자체계유층정색궤리적중요보충。
An in-house-built femtosecond laser ionization time-of-flight mass spectrometry (fs-LI-TOFMS)has been applied to the multi-elemental analysis of porcelain glaze from Yaozhou kiln.The samples are selected representing products of different dy-nasties,including Tang,Five,Song,Jin,and Ming Dynasty.For exploring the colorative mechanism of Yaozhou porcelain through the elemental analysis of the glaze,the effects of all potential coloring elements,especially transition elements,were considered.There was a speculation that the typical Co-Cr-Fe-Mn recipe was used in the fabrication of Yaozhou black glaze;the low content of Fe and high content of Ni resulted in the porcelain of white glaze;an increase content of P could lead the porcelain to be yellow-glazed.Undoubtedly,this research is an important supplement to the study of the colorative mechanism of the Yaozhou porcelain system.
