光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
Spectroscopy and Spectral Analysis
2015年
9期
2473-2477
,共5页
刘书华%贾鹏英%狄聪%李雪辰%杨帆
劉書華%賈鵬英%狄聰%李雪辰%楊帆
류서화%가붕영%적총%리설신%양범
大气压辉光放电%伏安特性%发射光谱%分子振动温度
大氣壓輝光放電%伏安特性%髮射光譜%分子振動溫度
대기압휘광방전%복안특성%발사광보%분자진동온도
Atmospheric pressure glow discharge%Voltage-current characteristics%Optical emission spectrum%Vibrational tem-perature
大气压均匀放电等离子体在工业领域具有非常广泛的应用前景,它是利用直流电源激励的空心针-板放电装置,以氩气为工作气体在大气压空气中产生均匀稳定的放电。对氩气流量和气隙间距对辉光放电发光特性的关系进行了研究,结果表明放电所产生的等离子体柱连接两个电极,发光较为均匀(观察不到放电丝)。在板电极附近放电等离子体柱直径最大,最大直径随着电流和气流的增大而增大。放电伏安特性研究发现,与低气压辉光放电相类似,两电极间的电压随着电流的增大而减小,并且随气流和气隙间距的增大而增大。对该大气压直流均匀放电在扫描范围为330~450 nm 的光学发射光谱进行分析,获得了放电等离子体的分子振动温度和谱线强度比 I 391.4/I 337.1随氩气流量和气隙间距的变化关系。I 391.4/I 337.1均随流量和气隙间距的增大而降低。对等离子体柱的 I 391.4/I 337.1沿气流方向(等离子体柱轴向)进行了空间分辨测量,并进行了定性分析,结果表明,振动温度及电子平均能量随着远离空心针口距离的增大而增大。这些结果对大气压辉光放电在工业中的应用具有重要意义。
大氣壓均勻放電等離子體在工業領域具有非常廣汎的應用前景,它是利用直流電源激勵的空心針-闆放電裝置,以氬氣為工作氣體在大氣壓空氣中產生均勻穩定的放電。對氬氣流量和氣隙間距對輝光放電髮光特性的關繫進行瞭研究,結果錶明放電所產生的等離子體柱連接兩箇電極,髮光較為均勻(觀察不到放電絲)。在闆電極附近放電等離子體柱直徑最大,最大直徑隨著電流和氣流的增大而增大。放電伏安特性研究髮現,與低氣壓輝光放電相類似,兩電極間的電壓隨著電流的增大而減小,併且隨氣流和氣隙間距的增大而增大。對該大氣壓直流均勻放電在掃描範圍為330~450 nm 的光學髮射光譜進行分析,穫得瞭放電等離子體的分子振動溫度和譜線彊度比 I 391.4/I 337.1隨氬氣流量和氣隙間距的變化關繫。I 391.4/I 337.1均隨流量和氣隙間距的增大而降低。對等離子體柱的 I 391.4/I 337.1沿氣流方嚮(等離子體柱軸嚮)進行瞭空間分辨測量,併進行瞭定性分析,結果錶明,振動溫度及電子平均能量隨著遠離空心針口距離的增大而增大。這些結果對大氣壓輝光放電在工業中的應用具有重要意義。
대기압균균방전등리자체재공업영역구유비상엄범적응용전경,타시이용직류전원격려적공심침-판방전장치,이아기위공작기체재대기압공기중산생균균은정적방전。대아기류량화기극간거대휘광방전발광특성적관계진행료연구,결과표명방전소산생적등리자체주련접량개전겁,발광교위균균(관찰불도방전사)。재판전겁부근방전등리자체주직경최대,최대직경수착전류화기류적증대이증대。방전복안특성연구발현,여저기압휘광방전상유사,량전겁간적전압수착전류적증대이감소,병차수기류화기극간거적증대이증대。대해대기압직류균균방전재소묘범위위330~450 nm 적광학발사광보진행분석,획득료방전등리자체적분자진동온도화보선강도비 I 391.4/I 337.1수아기류량화기극간거적변화관계。I 391.4/I 337.1균수류량화기극간거적증대이강저。대등리자체주적 I 391.4/I 337.1연기류방향(등리자체주축향)진행료공간분변측량,병진행료정성분석,결과표명,진동온도급전자평균능량수착원리공심침구거리적증대이증대。저사결과대대기압휘광방전재공업중적응용구유중요의의。
Atmosphere pressure uniform plasma has the broad application prospect in the industrial field.Using hollow needle cathode-plate anode device excited by direct-current voltage,a uniform and stable glow discharge is generated at atmospheric pressure in ambient air with argon used as working gas.The influence of the experimental parameters (including gas flow rate and the gas gap width)on discharge has been investigated by optical method.It can be found that a glow-discharge plasma col-umn can bridge the two electrodes.The plasma column is uniform,and no filaments can be discerned.Near the plate electrode, the diameter of the plasma column is largest of all positions.The maximal diameter of the plasma column increases with increas-ing the discharge current or the gas flow rate.Through electrical method,the voltage-current characteristic has been investiga-ted.It has been found that the discharge voltage decreases with increasing the current which is similar with the characteristic of glow discharge in low pressure.It increases with increasing the gas gap width or the gas flow rate.By analyzing the optical emis-sion spectrum scanning from 330 to 450 nm emitted from the direct-current glow discharge,the molecular vibrational tempera-ture and the intensity ratio of spectral lines I 391.4/I 337.1 have been investigated as functions of the gas flow rate and gas gap width. Results indicate that both the vibrational temperature and the intensity ratio of spectral lines I 391.4/I 337.1 decrease with increasing the gas flow rate or the gas gap width.In addition,the molecular vibrational temperature and the intensity ratio of spectral lines I 391.4/I 337.1 have been investigated in spatial resolution along the direction of gas flow(plasma column axial),and give a qualita-tive analysis as well.It is found that the vibrational temperature and the average electron energy increase with increasing the dis-tance from the hollow needle cathode.These results are important to the industrial applications of glow discharge.