CAJ | 학술논문

将改性的纳米蒙脱土（MMT）和官能化的多壁碳纳米管（MWCNTs）进行复合，然后负载 TiCl4催化组分，制备出纳米载体 Ziegler-Natta 催化剂，最后进行乙烯原位聚合得到含有多维纳米材料的聚乙烯基复合材料。通过调控纳米载体中两种材料的组成，研究蒙脱土／碳纳米管组成对纳米复合材料性能的影响。结果表明：纳米蒙脱土、改性碳纳米管复合作为催化剂的载体，能够得到高活性的乙烯聚合催化剂。两种纳米材料组成的改变，会影响聚乙烯复合材料的力学性能。当多壁碳纳米管与蒙脱土比例为1∶1时，所得到的复合材料的拉伸强度为38．7MPa。
장개성적납미몽탈토（MMT）화관능화적다벽탄납미관（MWCNTs）진행복합，연후부재 TiCl4최화조분，제비출납미재체 Ziegler-Natta 최화제，최후진행을희원위취합득도함유다유납미재료적취을희기복합재료。통과조공납미재체중량충재료적조성，연구몽탈토／탄납미관조성대납미복합재료성능적영향。결과표명：납미몽탈토、개성탄납미관복합작위최화제적재체，능구득도고활성적을희취합최화제。량충납미재료조성적개변，회영향취을희복합재료적역학성능。당다벽탄납미관여몽탈토비례위1∶1시，소득도적복합재료적랍신강도위38．7MPa。
Several heterogeneous Ziegler-Natta catalysts were prepared by loading TiCl4 using mixture of modified montmorillonite (MMT)and functionalized muti-walled carbon nanotubes (MWCNTs)as effective composite nanofillers.The polyethylene nanocomposites were produced by in-situ polymeri-zation with these catalysts.The effect of composition of MMT and MWCNTs on the mechanical prop-erties of polyethylene nanocomposite was investigated.The results show that highly active polymeri-zation catalyst with the nanofillers containing MMT and modified MWCNTs can be obtained.The composition of nanofiller has a remarkable influence on mechanical properties of polyethylene nano-composite.The maximum tensile strength of polyethylene nanocomposite is 38.7MPa using the mass ratio of MMT to MWCNTs of 1∶1.