浙江化工
浙江化工
절강화공
Zhejiang Chemical Industry
2015年
9期
43-46
,共4页
何田%陶佳炬%王凯%陈珈%刘斌
何田%陶佳炬%王凱%陳珈%劉斌
하전%도가거%왕개%진가%류빈
BODIPY%荧光染料%合成%表征%光学性能
BODIPY%熒光染料%閤成%錶徵%光學性能
BODIPY%형광염료%합성%표정%광학성능
BODIPY%fluorescent dye%synthesis%characterization%optical properties
本文通过钯催化偶联反应，成功地将三异丙基硅基乙炔引入到BODIPY 母体结构的3，5-位上，合成了一种新型的BODIPY荧光染料。通过核磁氢谱、红外光谱、质谱等表征手段对化合物进行了详细地结构表征，并通过紫外可见吸收和荧光光谱对其光学性能进行了研究。
本文通過鈀催化偶聯反應，成功地將三異丙基硅基乙炔引入到BODIPY 母體結構的3，5-位上，閤成瞭一種新型的BODIPY熒光染料。通過覈磁氫譜、紅外光譜、質譜等錶徵手段對化閤物進行瞭詳細地結構錶徵，併通過紫外可見吸收和熒光光譜對其光學性能進行瞭研究。
본문통과파최화우련반응，성공지장삼이병기규기을결인입도BODIPY 모체결구적3，5-위상，합성료일충신형적BODIPY형광염료。통과핵자경보、홍외광보、질보등표정수단대화합물진행료상세지결구표정，병통과자외가견흡수화형광광보대기광학성능진행료연구。
In this article, a new BODIPY-based fluorescent dye was synthesized by introduction of (tri-isopropylsilyl) acetylene to 3, 5-position of the BODIPY core under palladium-catalyzed Sonogashira cou-pling reaction condition. The structure of this compound was confirmed by 1H NMR, Fourier transform in-frared (FT-IR) spectroscopies, mass spectrum, and its optical properties was then investigated by UV–vis absorption, photoluminescence (PL) spectroscopies.
