华侨大学学报(自然科学版)
華僑大學學報(自然科學版)
화교대학학보(자연과학판)
Journal of Huaqiao University (Natural Science)
2015年
6期
677-682
,共6页
碳纳米材料%功能化%Diels-Alder 反应%巯基-烯点击反应
碳納米材料%功能化%Diels-Alder 反應%巰基-烯點擊反應
탄납미재료%공능화%Diels-Alder 반응%구기-희점격반응
carbon nanomaterials%functionalization%Diels-Alder reaction%thiol-ene click reaction
碳纳米管、富勒烯、石墨烯等碳纳米材料在水和有机溶剂中的溶解性不理想,导致在一定程度上限制了进一步的应用。文中综述了近几年无铜催化的点击反应,如 Diels-Alder 反应、巯基-烯点击反应等对碳纳米材料的化学修饰,并对其发展和应用前景进行了展望。
碳納米管、富勒烯、石墨烯等碳納米材料在水和有機溶劑中的溶解性不理想,導緻在一定程度上限製瞭進一步的應用。文中綜述瞭近幾年無銅催化的點擊反應,如 Diels-Alder 反應、巰基-烯點擊反應等對碳納米材料的化學脩飾,併對其髮展和應用前景進行瞭展望。
탄납미관、부륵희、석묵희등탄납미재료재수화유궤용제중적용해성불이상,도치재일정정도상한제료진일보적응용。문중종술료근궤년무동최화적점격반응,여 Diels-Alder 반응、구기-희점격반응등대탄납미재료적화학수식,병대기발전화응용전경진행료전망。
The poor solubility in water and organic solvents of carbon nanomaterials,such as carbon nanotubes,fullerene and graphene,limits its further application in part.In this paper,the application of the copper-free click reaction (such as Diels-Alder reaction and thiol-ene click reaction)on the functionalization of the carbon nanomaterials is reviewed.In addi-tion,the trend of its development is also discussed.