CAJ | 학술논문

综述了负载型磷化镍（Ni2P）催化剂的制备方法（还原法、溶剂热法和热解还原法）及其在石油化工领域中应用（加氢脱硫、加氢脱氮、加氢脱氯、加氢脱氧）的研究进展，并分析了催化剂制备方法的优劣。负载型Ni2P催化剂因其催化加氢、脱氢活性高，在烷烃异构化反应中表现出优良的活性，是一类新型的烷烃异构化催化剂。对负载型Ni2P催化剂的发展前景进行了展望，制备更高分散性、更高活性的催化剂将是今后研究的重点。
종술료부재형린화얼（Ni2P）최화제적제비방법（환원법、용제열법화열해환원법）급기재석유화공영역중응용（가경탈류、가경탈담、가경탈록、가경탈양）적연구진전，병분석료최화제제비방법적우렬。부재형Ni2P최화제인기최화가경、탈경활성고，재완경이구화반응중표현출우량적활성，시일류신형적완경이구화최화제。대부재형Ni2P최화제적발전전경진행료전망，제비경고분산성、경고활성적최화제장시금후연구적중점。
Progresses in the preparation and application of supported nickel phosphide catalysts(Ni2P) for hydrodesulfurization,hydrodenitrogenation,hydrodechlorination and hydrodeoxygenation in petrochemical industry were reviewed. The preparation methods,namely reduction method,solvothermal method and thermal decomposition method,were compared and analyzed. The supported Ni2P catalysts revealed good performances in then-para?ns hydroisomerization due to their high activity in the catalytic hydrogenation and dehydrogenation. It was forecasted that preparing Ni2P with higher dispersity and activity would become focal point in the future research.