石油化工
石油化工
석유화공
Petrochemical Technology
2015年
10期
1149-1156
,共8页
线性氢甲酰化%铑催化剂%膦配体
線性氫甲酰化%銠催化劑%膦配體
선성경갑선화%로최화제%련배체
linear hydroformylation%rhodium catalyst%phosphine ligands
介绍了氢甲酰化反应机理；综述了线性氢甲酰化配体的发展过程，包括双齿膦配体、三齿膦配体及四齿膦配体，双齿膦配体中重点介绍了Bisbi系列配体、Xantphos系列配体和具有大位阻的含亚磷酸酯键的Biphephos系列配体的结构及应用；并从配体的设计出发，简要地介绍了氢甲酰化的机理和影响线性氢甲酰化反应选择性的因素。对如何推动我国线性氢甲酰化工业的发展提出了展望。
介紹瞭氫甲酰化反應機理；綜述瞭線性氫甲酰化配體的髮展過程，包括雙齒膦配體、三齒膦配體及四齒膦配體，雙齒膦配體中重點介紹瞭Bisbi繫列配體、Xantphos繫列配體和具有大位阻的含亞燐痠酯鍵的Biphephos繫列配體的結構及應用；併從配體的設計齣髮，簡要地介紹瞭氫甲酰化的機理和影響線性氫甲酰化反應選擇性的因素。對如何推動我國線性氫甲酰化工業的髮展提齣瞭展望。
개소료경갑선화반응궤리；종술료선성경갑선화배체적발전과정，포괄쌍치련배체、삼치련배체급사치련배체，쌍치련배체중중점개소료Bisbi계렬배체、Xantphos계렬배체화구유대위조적함아린산지건적Biphephos계렬배체적결구급응용；병종배체적설계출발，간요지개소료경갑선화적궤리화영향선성경갑선화반응선택성적인소。대여하추동아국선성경갑선화공업적발전제출료전망。
The mechanism of linear hydroformylation and the development history of ligands for the linear hydroformylation were reviewed briefl y. Among bidentate ligands,tridentate ligands and tetradentate ligands,the Bisbi type ligands,Xantphos type ligands and Biphephos ligands with bulky substituting groups were discussed. Moreover,the mechanism and the factors infl uencing the regioselectivity of the linear hydroformylation were introduced. The prospects on how to promote the application of the liner hydrofomylation in industry were predicted.
