光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
Spectroscopy and Spectral Analysis
2015年
10期
2792-2796
,共5页
万福%陈伟根%顾朝亮%邹经鑫%杜玲玲%漆薇%周渠
萬福%陳偉根%顧朝亮%鄒經鑫%杜玲玲%漆薇%週渠
만복%진위근%고조량%추경흠%두령령%칠미%주거
腔增强吸收光谱技术%光学反馈%乙烷%溶解气体分析
腔增彊吸收光譜技術%光學反饋%乙烷%溶解氣體分析
강증강흡수광보기술%광학반궤%을완%용해기체분석
Cavity-enhanced absorption spectroscopy%Optical feedback%Ethane%Dissolved gas analysis
乙烷是电力变压器油中溶解的主要故障特征气体之一,其高精度、高灵敏度检测是进行油中溶解气体分析的关键。基于光反馈原理及腔增强吸收光谱技术,结合量子级联激光器,建立了一套变压器油中溶解乙烷气体检测系统。基于腔内单腔模对称理论,通过LabVIEW编程来实现反馈光与腔谐振的相位匹配。研究并实现了光学反馈效应(激光将在延迟一定的时间后,返回激光腔并锁定腔模式共振频率)、偶数和奇数模式效应(交替出现强度较大和较小的腔模式)、激光器阈值电流降低效应(约1.2 mA)。利用腔衰荡光谱检测技术测得的系统有效反射率、腔品质因素分别为99.978%和7138.4,系统光谱分辨率达到0.0052 cm -1。标准大气压、温度20℃下,1 s的积分时间内,对乙烷P Q3吸收线进行检测,系统检测准确率及检测极限分别达到95.72%±0.17%和(1.97±0.06)×10-3μL?L -1,满足了变压器油中溶解乙烷气体检测的需要。
乙烷是電力變壓器油中溶解的主要故障特徵氣體之一,其高精度、高靈敏度檢測是進行油中溶解氣體分析的關鍵。基于光反饋原理及腔增彊吸收光譜技術,結閤量子級聯激光器,建立瞭一套變壓器油中溶解乙烷氣體檢測繫統。基于腔內單腔模對稱理論,通過LabVIEW編程來實現反饋光與腔諧振的相位匹配。研究併實現瞭光學反饋效應(激光將在延遲一定的時間後,返迴激光腔併鎖定腔模式共振頻率)、偶數和奇數模式效應(交替齣現彊度較大和較小的腔模式)、激光器閾值電流降低效應(約1.2 mA)。利用腔衰盪光譜檢測技術測得的繫統有效反射率、腔品質因素分彆為99.978%和7138.4,繫統光譜分辨率達到0.0052 cm -1。標準大氣壓、溫度20℃下,1 s的積分時間內,對乙烷P Q3吸收線進行檢測,繫統檢測準確率及檢測極限分彆達到95.72%±0.17%和(1.97±0.06)×10-3μL?L -1,滿足瞭變壓器油中溶解乙烷氣體檢測的需要。
을완시전력변압기유중용해적주요고장특정기체지일,기고정도、고령민도검측시진행유중용해기체분석적관건。기우광반궤원리급강증강흡수광보기술,결합양자급련격광기,건립료일투변압기유중용해을완기체검측계통。기우강내단강모대칭이론,통과LabVIEW편정래실현반궤광여강해진적상위필배。연구병실현료광학반궤효응(격광장재연지일정적시간후,반회격광강병쇄정강모식공진빈솔)、우수화기수모식효응(교체출현강도교대화교소적강모식)、격광기역치전류강저효응(약1.2 mA)。이용강쇠탕광보검측기술측득적계통유효반사솔、강품질인소분별위99.978%화7138.4,계통광보분변솔체도0.0052 cm -1。표준대기압、온도20℃하,1 s적적분시간내,대을완P Q3흡수선진행검측,계통검측준학솔급검측겁한분별체도95.72%±0.17%화(1.97±0.06)×10-3μL?L -1,만족료변압기유중용해을완기체검측적수요。
Ethane is one of major fault characteristic gases dissolved in power transformer ,the detection of Ethane with high ac‐curacy and sensitivity is the key of dissolved gas analysis .In this paper ,based on optical feedback theory and cavity‐enhanced ab‐sorption spectroscopy ,combined with quantum cascade laser ,a detection system for dissolved gas C2 H6 in transformer oil was built up .Based on the symmetry of the individual cavity modes ,the phase matching of returning light in resonance with the cavi‐ty was achieved through LabVIEW codes .The optical feedback effect that the emitted light return to the laser cavity after a small delay time and lock to the resonance frequency of cavity ,even and odd modes effect that the higher modes and lower modes structure will build up alternatively ,and threshold current lowering effect of about 1.2 mA were studied and achieved .By cavity ring‐down spectroscopy ,the effective reflectivity of 99.978% and cavity finesse of 7 138.4 is obtained respectively .The fre‐quency selectivity is 0.005 2 cm-1 .With an acquisition time of 1s ,this optical system allows detection for the P Q3 band of C2 H6 with high accuracy of 95.72% ± 0.17% and detection limit of (1.97 ± 0.06) × 10-3 μL?L -1 at atmospheric pressure and tem‐perature of 20 ℃ ,which lays a foundation for fault diagnose from dissolved gas analysis .