光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
Spectroscopy and Spectral Analysis
2015年
10期
2703-2707,2729
,共6页
韩育宏%贾鹏英%何寿杰%张子生
韓育宏%賈鵬英%何壽傑%張子生
한육굉%가붕영%하수걸%장자생
微间隙%均匀放电%放电功率%电子平均能量
微間隙%均勻放電%放電功率%電子平均能量
미간극%균균방전%방전공솔%전자평균능량
Micro-gap%Uniform discharge%Discharge power%Electron average energy
大气压空气中介质阻挡均匀放电产生的等离子体在工业领域具有广阔的应用前景,为研究其产生条件及机理,利用微间隙介质阻挡放电装置,在大气压空气中实现了均匀放电。电学实验结果表明,低电压时电流波形在电压每半个周期存在若干个脉冲宽度很小的脉冲,肉眼观察到大量的微放电丝,随着外加电压增加,放电功率逐渐增加,放电空间内微放细丝增多。当电压增大到9.2 kV时,电流波形在电压每半个周期只存在一个宽度较大(约5.5μs)强度较强的脉冲,观察不到微放电丝,微放电最终扩展叠加形成均匀放电。采集了光谱范围为330~420 nm的发射光谱,氮分子第二正带系337.1 nm的谱线强度明显比氮分子离子第一负带系391.4 nm的强。将337.1 nm谱线的强度归一,391.4 nm谱线的强度即反应了电子平均能量的大小,同时拟合计算了反映分子内部能量的氮分子振动温度。结果表明电子平均能量和分子内部能量都随外加电压的增加而降低。表明放电空间电场能量较低时不容易形成丝状放电,均匀放电模式中电子平均能量比微放电丝放电模式中的低。这些结果对于空气中介质阻挡均匀放电在工业应用方面具有一定的指导意义。
大氣壓空氣中介質阻擋均勻放電產生的等離子體在工業領域具有廣闊的應用前景,為研究其產生條件及機理,利用微間隙介質阻擋放電裝置,在大氣壓空氣中實現瞭均勻放電。電學實驗結果錶明,低電壓時電流波形在電壓每半箇週期存在若榦箇脈遲寬度很小的脈遲,肉眼觀察到大量的微放電絲,隨著外加電壓增加,放電功率逐漸增加,放電空間內微放細絲增多。噹電壓增大到9.2 kV時,電流波形在電壓每半箇週期隻存在一箇寬度較大(約5.5μs)彊度較彊的脈遲,觀察不到微放電絲,微放電最終擴展疊加形成均勻放電。採集瞭光譜範圍為330~420 nm的髮射光譜,氮分子第二正帶繫337.1 nm的譜線彊度明顯比氮分子離子第一負帶繫391.4 nm的彊。將337.1 nm譜線的彊度歸一,391.4 nm譜線的彊度即反應瞭電子平均能量的大小,同時擬閤計算瞭反映分子內部能量的氮分子振動溫度。結果錶明電子平均能量和分子內部能量都隨外加電壓的增加而降低。錶明放電空間電場能量較低時不容易形成絲狀放電,均勻放電模式中電子平均能量比微放電絲放電模式中的低。這些結果對于空氣中介質阻擋均勻放電在工業應用方麵具有一定的指導意義。
대기압공기중개질조당균균방전산생적등리자체재공업영역구유엄활적응용전경,위연구기산생조건급궤리,이용미간극개질조당방전장치,재대기압공기중실현료균균방전。전학실험결과표명,저전압시전류파형재전압매반개주기존재약간개맥충관도흔소적맥충,육안관찰도대량적미방전사,수착외가전압증가,방전공솔축점증가,방전공간내미방세사증다。당전압증대도9.2 kV시,전류파형재전압매반개주기지존재일개관도교대(약5.5μs)강도교강적맥충,관찰불도미방전사,미방전최종확전첩가형성균균방전。채집료광보범위위330~420 nm적발사광보,담분자제이정대계337.1 nm적보선강도명현비담분자리자제일부대계391.4 nm적강。장337.1 nm보선적강도귀일,391.4 nm보선적강도즉반응료전자평균능량적대소,동시의합계산료반영분자내부능량적담분자진동온도。결과표명전자평균능량화분자내부능량도수외가전압적증가이강저。표명방전공간전장능량교저시불용역형성사상방전,균균방전모식중전자평균능량비미방전사방전모식중적저。저사결과대우공기중개질조당균균방전재공업응용방면구유일정적지도의의。
The plasmas generated by dielectric barrier discharge in atmospheric pressure air have wide application prospect in in‐dustry .In order to study generation condition and mechanism ,the dielectric barrier uniform discharge in atmospheric pressure air has been studied experimentally with a micro‐gap discharge device .Results of electrical characteristics indicate that it exist several current pulses with short width in half period of the applied voltage at a low voltage ,a large number of micro‐discharge filaments are observed .The discharge power increases with increasing peak value of applied voltage ,the micro‐discharge fila‐ments increase meanwhile .When the peak of applied voltage reaches to 9.2 kV ,only a discharge hump with a width of about 5.5μs appears in a half period of the applied voltage ,micro‐discharge filaments cannot be discerned .The uniform discharge has been obtained finally as the micro‐discharge filaments extend and superimpose randomly .The emission spectrum of dielectric barrier discharge scanning from 330 to 420 nm is collected .It is found that the intensity of 337.1 nm is stronger than that of 391.4 nm . If the intensity of 337.1 nm is considered as the datum reference ,the intensity of 391.4 nm shows the magnitude of electron av‐erage energy .The molecule internal energy is evaluated by vibration temperature .The electron average energy and molecule in‐ternal energy have been investigated by optical emission spectra .It is found that both of them decrease with increasing the ap‐plied voltage .Results indicate that it is not easy to form filamentary discharge when the electrical energy is lower .The average electron energy of uniform discharge is lower than that of the filamentary discharge .These results are of great significance to the application of dielectric barrier uniform discharge obtained in air at atmospheric pressure .