光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
Spectroscopy and Spectral Analysis
2015年
10期
2752-2756
,共5页
朱亨银%傅霞萍%游贵荣%何金成
硃亨銀%傅霞萍%遊貴榮%何金成
주형은%부하평%유귀영%하금성
莲子%近红外光谱%光谱分析%无损检测
蓮子%近紅外光譜%光譜分析%無損檢測
련자%근홍외광보%광보분석%무손검측
Lotus seed%Near infrared spectroscopy%Spectral analysis%Nondestructive detection
通过提取采后不同时期的莲子、莲仁的近红外漫反射光谱特征,以莲子的可溶性固形物(SSC )和干物质含量(DM )为指标进行定量和定性分析。利用偏最小二乘回归(PLSR)分析和距离判别分析(DA )计算所得的结果表明:SSC和DM含量与莲子、莲仁的吸收光谱特征具有明显相关。莲子SSC、DM 的PLSR模型在5941~12480 cm-1谱区综合性能较好,预测相关系数( r1)分别为0.74和82,校正相关系数( r2)分别为0.82和0.84,留一交互相关系数(r3)分别为0.72和0.71。莲仁SSC的PLSR模型在7891~9310 cm-1谱区综合性能较好, r1为0.79, r2为0.84, r3为0.77。DM 的 PLSR模型在全光谱的综合性能较好, r1为0.92, r2为0.89, r3为0.82。莲子在5400~7885 cm -1谱区的判别性能较好,正确率达84.2%,而莲仁在9226~12480 cm-1谱区的判别性能较好,正确率达90.8%。对不同年份和有膜有芯的干莲仁进行DA判别的精度可达98.9%。研究表明近红外检测技术可用于莲子和莲仁的SSC和DM含量的定量分析及储存期的定性判别,还可对不同年份和有膜有芯的干莲仁进行判别。
通過提取採後不同時期的蓮子、蓮仁的近紅外漫反射光譜特徵,以蓮子的可溶性固形物(SSC )和榦物質含量(DM )為指標進行定量和定性分析。利用偏最小二乘迴歸(PLSR)分析和距離判彆分析(DA )計算所得的結果錶明:SSC和DM含量與蓮子、蓮仁的吸收光譜特徵具有明顯相關。蓮子SSC、DM 的PLSR模型在5941~12480 cm-1譜區綜閤性能較好,預測相關繫數( r1)分彆為0.74和82,校正相關繫數( r2)分彆為0.82和0.84,留一交互相關繫數(r3)分彆為0.72和0.71。蓮仁SSC的PLSR模型在7891~9310 cm-1譜區綜閤性能較好, r1為0.79, r2為0.84, r3為0.77。DM 的 PLSR模型在全光譜的綜閤性能較好, r1為0.92, r2為0.89, r3為0.82。蓮子在5400~7885 cm -1譜區的判彆性能較好,正確率達84.2%,而蓮仁在9226~12480 cm-1譜區的判彆性能較好,正確率達90.8%。對不同年份和有膜有芯的榦蓮仁進行DA判彆的精度可達98.9%。研究錶明近紅外檢測技術可用于蓮子和蓮仁的SSC和DM含量的定量分析及儲存期的定性判彆,還可對不同年份和有膜有芯的榦蓮仁進行判彆。
통과제취채후불동시기적련자、련인적근홍외만반사광보특정,이련자적가용성고형물(SSC )화간물질함량(DM )위지표진행정량화정성분석。이용편최소이승회귀(PLSR)분석화거리판별분석(DA )계산소득적결과표명:SSC화DM함량여련자、련인적흡수광보특정구유명현상관。련자SSC、DM 적PLSR모형재5941~12480 cm-1보구종합성능교호,예측상관계수( r1)분별위0.74화82,교정상관계수( r2)분별위0.82화0.84,류일교호상관계수(r3)분별위0.72화0.71。련인SSC적PLSR모형재7891~9310 cm-1보구종합성능교호, r1위0.79, r2위0.84, r3위0.77。DM 적 PLSR모형재전광보적종합성능교호, r1위0.92, r2위0.89, r3위0.82。련자재5400~7885 cm -1보구적판별성능교호,정학솔체84.2%,이련인재9226~12480 cm-1보구적판별성능교호,정학솔체90.8%。대불동년빈화유막유심적간련인진행DA판별적정도가체98.9%。연구표명근홍외검측기술가용우련자화련인적SSC화DM함량적정량분석급저존기적정성판별,환가대불동년빈화유막유심적간련인진행판별。
By extracting the Near Infrared (NIR) diffuse reflectance spectral characteristics from the post‐harvest lotus seeds in different storage periods ,the quantitative and qualitative analysis were applied to lotus seeds with the Soluble Solids Content (SSC) and dry matter content (DM ) as criteria .The results of the Partial Least Squares Regression (PLSR) and distance dis‐crimination (DA) models showed that the absorption spectra of lotus seeds and lotus kernels has clear relations to their SSC and DM .The PLSR models of SSC and DM of lotus seeds had the best performance in 5 941~12 480 cm -1 spectral region in this study .Their correlation coefficients of prediction were 0 .74 and 0 .82 ,and the correlation coefficients of calibration were 0.82 and 0.84 ,and the correlation coefficients of leave one out cross validation were 0.72 and 0.71 .The PLSR model of SSC of lotus kernels was better in 7 891~9 310 cm-1 spectral region .Its correlation coefficient of prediction was 0.79 ,and the correlation coefficient of calibration was 0.84 ,and the correlation coefficient of leave one out cross validation was 0.77 .The PLSR model of DM of lotus kernels is better in the full spectral region .Its correlation coefficient of prediction was 0.92 ,and the correlation co‐efficient of calibration was 0 .89 ,and the correlation coefficient of leave one out cross validation was 0 .82 .For lotus seeds ,the DA model in 5 400~7 885 cm -1 spectral region is the best with a correctness of 84.2% .And for lotus kernels ,the DA model in 9 226~12 480 cm-1 spectral region is the best with a correctness of 90.8% .For dry lotus kernels ,the discriminant accuracy of the DA model is 98.9% in the optimal spectral region .All kernels with membrane and plumule were correctly discriminated . This research shows that the NIR spectroscopy technique can be used to determine SSC and DM content of lotus seeds and lotus kernels ,as well as to discriminate their freshness and also to discriminate dry lotus kernels of different age and the kernels with membrane and plumule .