光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
Spectroscopy and Spectral Analysis
2015年
10期
2895-2900
,共6页
X射线荧光%激光拉曼光谱%中国蓝%釉砂%古代玻璃
X射線熒光%激光拉曼光譜%中國藍%釉砂%古代玻璃
X사선형광%격광랍만광보%중국람%유사%고대파리
X-ray fluorescence spectrometry%Laser Raman spectroscopy%Chinese blue%Faience%ancient glass
结合X射线荧光光谱、拉曼光谱和X射线衍射分析，对甘肃马家塬战国墓地M 4出土的11件装饰性硅酸盐珠饰进行了无损分析研究。依据分析结果将这些样品划分为钠钙硅酸盐玻璃、铅钡硅酸盐玻璃和釉砂三种类型。化学成分分析结果表明：钠钙硅酸盐蜻蜓眼玻璃珠的蓝色眼珠部分采用Co2＋着色。拉曼光谱分析在铅钡体系硅酸盐样品中检测到了人工合成的硅酸钡铜系中国蓝和中国紫颜料，在钠钙蜻蜓眼玻璃的白色区域检测到了锑酸钙（CaSb2 O6）乳浊剂／着色剂。结合已有的研究结果，探讨了所分析样品的可能来源及其反映的早期文化和技术交流状况。含有中国蓝、中国紫的装饰性珠子的制作材料和工艺应当是受到当时秦人的影响。而钠钙蜻蜓眼珠的成分特点，又与新疆等西北地区出土的同类珠子有相似之处。可见西戎人在玻璃制作技术方面同时受到北方草原民族文化和秦文化的共同影响。这批样品中以泥芯和玻璃化材料共同组成的装饰珠子，可能是从釉砂珠向玻璃珠的过渡类型，这对于研究我国玻璃的起源问题提供了新的参考资料。
結閤X射線熒光光譜、拉曼光譜和X射線衍射分析，對甘肅馬傢塬戰國墓地M 4齣土的11件裝飾性硅痠鹽珠飾進行瞭無損分析研究。依據分析結果將這些樣品劃分為鈉鈣硅痠鹽玻璃、鉛鋇硅痠鹽玻璃和釉砂三種類型。化學成分分析結果錶明：鈉鈣硅痠鹽蜻蜓眼玻璃珠的藍色眼珠部分採用Co2＋著色。拉曼光譜分析在鉛鋇體繫硅痠鹽樣品中檢測到瞭人工閤成的硅痠鋇銅繫中國藍和中國紫顏料，在鈉鈣蜻蜓眼玻璃的白色區域檢測到瞭銻痠鈣（CaSb2 O6）乳濁劑／著色劑。結閤已有的研究結果，探討瞭所分析樣品的可能來源及其反映的早期文化和技術交流狀況。含有中國藍、中國紫的裝飾性珠子的製作材料和工藝應噹是受到噹時秦人的影響。而鈉鈣蜻蜓眼珠的成分特點，又與新疆等西北地區齣土的同類珠子有相似之處。可見西戎人在玻璃製作技術方麵同時受到北方草原民族文化和秦文化的共同影響。這批樣品中以泥芯和玻璃化材料共同組成的裝飾珠子，可能是從釉砂珠嚮玻璃珠的過渡類型，這對于研究我國玻璃的起源問題提供瞭新的參攷資料。
결합X사선형광광보、랍만광보화X사선연사분석，대감숙마가원전국묘지M 4출토적11건장식성규산염주식진행료무손분석연구。의거분석결과장저사양품화분위납개규산염파리、연패규산염파리화유사삼충류형。화학성분분석결과표명：납개규산염청정안파리주적람색안주부분채용Co2＋착색。랍만광보분석재연패체계규산염양품중검측도료인공합성적규산패동계중국람화중국자안료，재납개청정안파리적백색구역검측도료제산개（CaSb2 O6）유탁제／착색제。결합이유적연구결과，탐토료소분석양품적가능래원급기반영적조기문화화기술교류상황。함유중국람、중국자적장식성주자적제작재료화공예응당시수도당시진인적영향。이납개청정안주적성분특점，우여신강등서북지구출토적동류주자유상사지처。가견서융인재파리제작기술방면동시수도북방초원민족문화화진문화적공동영향。저비양품중이니심화파리화재료공동조성적장식주자，가능시종유사주향파리주적과도류형，저대우연구아국파리적기원문제제공료신적삼고자료。
This paper reports the analysis results of 11 decorated silicate beads samples excavated from Ma Jia‐yuan Warring State Cemetery ,Gan Su Province with the portable X‐ray fluorescence spectrometer ,laser Raman spectrometer and X‐ray dif‐fraction spectrometer .It is includes 3 types among these samples on the basis of their chemical composition ,NaO‐CaO‐SiO2 , PbO‐BaO‐SiO2 glass system ,and glassy faience .The blue part of the NaO‐CaO‐SiO2 glass sample was colored by Co2+ ,and Sb2O5 was discovered as opacifier .The results of Laser Raman analysis shows in some circle beads exits Chinese blue and Chinese purple .Combined with the existing research results the early cultural factors and technical exchange reflected from these samples are discussed .It shows that the material and craftsmanship of the beads contained Chinese blue and Chinese purple were affected by Qin Culture .But the composition of the Na‐Ca‐SiO2 glass eye bead is similar with those excavated from Xin Jiang area .It infers the technology of glass manufacture of the Xi Ron nationality was influenced by the Qin Culture and the grassland nationalities’ culture simultaneously .The faience bead composed with the inner core and the outer glassy layer is possible a kind of transitional type between the faience and the real glass .This information offers a new reference for the research of the origin of the glass technology in the ancient China .
