日用化学工业
日用化學工業
일용화학공업
China Surfactant Detergent & Cosmetics
2015年
11期
625-628
,共4页
李云哲%李运玲%宋永波%李俊
李雲哲%李運玲%宋永波%李俊
리운철%리운령%송영파%리준
磺基琥珀酸单酯二钠盐%Guerbet醇%合成%性能
磺基琥珀痠單酯二鈉鹽%Guerbet醇%閤成%性能
광기호박산단지이납염%Guerbet순%합성%성능
disodium sulfosuccinate%Guerbet alcohol%synthesis%performance
以Guerbet十六醇为原料,通过与顺丁烯二酸酐进行酯化反应再与亚硫酸钠发生磺化反应,制备了Guerbet十六醇磺基琥珀酸单酯二钠盐(HDSS ),采用 FTIR和1 HNMR对其结构进行表征,并对其性能进行考察。HDSS的γcmc为27.7 mN/m,3.0 g/L的HDSS溶液中帆布润湿时间为10 s,2.0 g/L的HDSS溶液在0.5和30 min时的泡沫体积分别为445和235 mL。上述结果表明HDSS具有优良的表面活性、润湿性和泡沫性能。
以Guerbet十六醇為原料,通過與順丁烯二痠酐進行酯化反應再與亞硫痠鈉髮生磺化反應,製備瞭Guerbet十六醇磺基琥珀痠單酯二鈉鹽(HDSS ),採用 FTIR和1 HNMR對其結構進行錶徵,併對其性能進行攷察。HDSS的γcmc為27.7 mN/m,3.0 g/L的HDSS溶液中帆佈潤濕時間為10 s,2.0 g/L的HDSS溶液在0.5和30 min時的泡沫體積分彆為445和235 mL。上述結果錶明HDSS具有優良的錶麵活性、潤濕性和泡沫性能。
이Guerbet십륙순위원료,통과여순정희이산항진행지화반응재여아류산납발생광화반응,제비료Guerbet십륙순광기호박산단지이납염(HDSS ),채용 FTIR화1 HNMR대기결구진행표정,병대기성능진행고찰。HDSS적γcmc위27.7 mN/m,3.0 g/L적HDSS용액중범포윤습시간위10 s,2.0 g/L적HDSS용액재0.5화30 min시적포말체적분별위445화235 mL。상술결과표명HDSS구유우량적표면활성、윤습성화포말성능。
Disodium Guerbet hexadecyl sulfosuccinate (HDSS)was synthesized through esterification of C16 Guerbet alcohol (2 -hexyl -1 -decanol)with maleic anhydride and sulfonation of the mono ester with Na2 SO3 . Structure of the HDSS was characterized by FTIR and 1 HNMR,and its performance was investigated. The γcmc of the HDSS is 27.7 mN/m,the wetting time of canvas in the HDSS aqueous solution (3.0 g/L)is 10 s,and the foam volume of HDSS (2.0 g/L)is 445 mL at 0.5 min and 235 mL at 30 min. The results indicated that the HDSS has good surface activity,wetting power and foaming performance.