贵金属
貴金屬
귀금속
Precious Metals
2015年
z1期
152-156
,共5页
何佳%赵文雅%何敏%刘新星%董海刚%谢建平
何佳%趙文雅%何敏%劉新星%董海剛%謝建平
하가%조문아%하민%류신성%동해강%사건평
生物冶金%大肠杆菌E.coli%工业废水%吸附%Pt(Ⅳ)%Pd(Ⅱ)
生物冶金%大腸桿菌E.coli%工業廢水%吸附%Pt(Ⅳ)%Pd(Ⅱ)
생물야금%대장간균E.coli%공업폐수%흡부%Pt(Ⅳ)%Pd(Ⅱ)
biological metallurgy%Escherichia coli%industrial wastewater%adsorption%Pt(IV)%Pd(II)
为了对云南某厂废水中的铂族金属Pt(Ⅳ)、Pd(Ⅱ)进行吸附回收ⅷ将大肠杆菌E.coli做为吸附剂ⅷ探讨其在较适工艺条件下的吸附率ⅷ并结合Pt(Ⅳ)、Pd(Ⅱ)的纯溶液吸附来探索E.coli对废水中铂族金属的吸附特性。Pt(Ⅳ)、Pd(Ⅱ)纯溶液吸附实验表明ⅷE.coli对两者吸附能力相当ⅷ吸附率分别为96.66%、97.68%?而在工业废水中ⅷE.coli对Pt(Ⅳ)的吸附率仅为19.5%ⅷPd(Ⅱ)的吸附率仍有97.20%。用SPSS软件对工业废水吸附结果进行显著性分析ⅷ综合吸附量、吸附率ⅷ可认为废水中存在的大量贱金属对 Pd(Ⅱ)的吸附没有产生影响ⅷE.coli 对 Pd(Ⅱ)表现除了较高的恒择吸附性?双相Pt(Ⅳ)-Pd(Ⅱ)溶液吸附实验也表现出了相似的结果。可见在Pt(Ⅳ)-Pd(Ⅱ)共存的溶液中ⅷE.coli对Pd(Ⅱ)具有较高恒择吸附性。
為瞭對雲南某廠廢水中的鉑族金屬Pt(Ⅳ)、Pd(Ⅱ)進行吸附迴收ⅷ將大腸桿菌E.coli做為吸附劑ⅷ探討其在較適工藝條件下的吸附率ⅷ併結閤Pt(Ⅳ)、Pd(Ⅱ)的純溶液吸附來探索E.coli對廢水中鉑族金屬的吸附特性。Pt(Ⅳ)、Pd(Ⅱ)純溶液吸附實驗錶明ⅷE.coli對兩者吸附能力相噹ⅷ吸附率分彆為96.66%、97.68%?而在工業廢水中ⅷE.coli對Pt(Ⅳ)的吸附率僅為19.5%ⅷPd(Ⅱ)的吸附率仍有97.20%。用SPSS軟件對工業廢水吸附結果進行顯著性分析ⅷ綜閤吸附量、吸附率ⅷ可認為廢水中存在的大量賤金屬對 Pd(Ⅱ)的吸附沒有產生影響ⅷE.coli 對 Pd(Ⅱ)錶現除瞭較高的恆擇吸附性?雙相Pt(Ⅳ)-Pd(Ⅱ)溶液吸附實驗也錶現齣瞭相似的結果。可見在Pt(Ⅳ)-Pd(Ⅱ)共存的溶液中ⅷE.coli對Pd(Ⅱ)具有較高恆擇吸附性。
위료대운남모엄폐수중적박족금속Pt(Ⅳ)、Pd(Ⅱ)진행흡부회수ⅷ장대장간균E.coli주위흡부제ⅷ탐토기재교괄공예조건하적흡부솔ⅷ병결합Pt(Ⅳ)、Pd(Ⅱ)적순용액흡부래탐색E.coli대폐수중박족금속적흡부특성。Pt(Ⅳ)、Pd(Ⅱ)순용액흡부실험표명ⅷE.coli대량자흡부능력상당ⅷ흡부솔분별위96.66%、97.68%?이재공업폐수중ⅷE.coli대Pt(Ⅳ)적흡부솔부위19.5%ⅷPd(Ⅱ)적흡부솔잉유97.20%。용SPSS연건대공업폐수흡부결과진행현저성분석ⅷ종합흡부량、흡부솔ⅷ가인위폐수중존재적대량천금속대 Pd(Ⅱ)적흡부몰유산생영향ⅷE.coli 대 Pd(Ⅱ)표현제료교고적항택흡부성?쌍상Pt(Ⅳ)-Pd(Ⅱ)용액흡부실험야표현출료상사적결과。가견재Pt(Ⅳ)-Pd(Ⅱ)공존적용액중ⅷE.coli대Pd(Ⅱ)구유교고항택흡부성。
To recover the platinum group metal Pt(IV) and Pd(II) in the waste water of a factory in Yunnan Province, the E.coliwas used as adsorbent to investigate the adsorption rate under better conditions and adsorption of pure Pt(IV), Pd(II) solution were used to explore the adsorption characteristics ofE.coli on the platinum group metals in wastewater. Pure Pt(IV) and Pd(II) solution adsorption experiments showed that two adsorption capacity of E.coli is equal, and the adsorption rate was 96.66% and 97.68% respectively; in industrial wastewater, the adsorption rate ofE.coli on Pt(IV) was 19.5%, and the adsorption rate of Pd(II) was still 97.20%. Analysis results of the adsorption results of industrial wastewater using SPSS software showed the adsorption of Pd(II) was not affected by the presence of a large number of base metals in wastewater, and theE.colishows Pd(II)-selective sorption behavior; the similar results were also demonstrated by Pt(IV)-Pd(II) solution adsorption experiments. In the solution of Pt (IV)-Pd (II), the E.coli has a high Pd(II)-selective adsorption property.