贵金属
貴金屬
귀금속
Precious Metals
2015年
z1期
108-112
,共5页
闫方存%滕媛%杨坚%康昆勇%严继康%易健宏%甘国友
閆方存%滕媛%楊堅%康昆勇%嚴繼康%易健宏%甘國友
염방존%등원%양견%강곤용%엄계강%역건굉%감국우
材料物理与化学%银导电浆料%有机载体%挥发性%触变性
材料物理與化學%銀導電漿料%有機載體%揮髮性%觸變性
재료물리여화학%은도전장료%유궤재체%휘발성%촉변성
material physics and chemistry%conductive silver paste%organic carrier%volatile%thixotropy
具有层次挥发性和良好的触变性的有机载体影响银导电浆料的印刷性和烧结性。实验采用丝网印刷工艺,在松油醇-丁基卡必醇-乙基纤维素体系中添加松节油、1,4-丁内酯、甘油、邻苯二甲酸二丁酯四种有机物调节有机载体的挥发性,另外探究在有机载体中添加氢化蓖麻油、聚酰胺蜡对有机载体的触变性的影响。发现,当松节油=10%、1,4-丁内酯=15%0、松油醇=35%、丁基卡必醇=10%、丙三醇=10%、邻苯二甲酸二丁酯=10%时溶剂具有良好的挥发性,挥发均匀,避免了集中挥发造成银膜气孔的产生。另外,当聚酰胺蜡质量分数为0.4%时,触变指数为1.9,有机载体具有较好的触变性,可有效改善银导电浆料的印刷性。
具有層次揮髮性和良好的觸變性的有機載體影響銀導電漿料的印刷性和燒結性。實驗採用絲網印刷工藝,在鬆油醇-丁基卡必醇-乙基纖維素體繫中添加鬆節油、1,4-丁內酯、甘油、鄰苯二甲痠二丁酯四種有機物調節有機載體的揮髮性,另外探究在有機載體中添加氫化蓖痳油、聚酰胺蠟對有機載體的觸變性的影響。髮現,噹鬆節油=10%、1,4-丁內酯=15%0、鬆油醇=35%、丁基卡必醇=10%、丙三醇=10%、鄰苯二甲痠二丁酯=10%時溶劑具有良好的揮髮性,揮髮均勻,避免瞭集中揮髮造成銀膜氣孔的產生。另外,噹聚酰胺蠟質量分數為0.4%時,觸變指數為1.9,有機載體具有較好的觸變性,可有效改善銀導電漿料的印刷性。
구유층차휘발성화량호적촉변성적유궤재체영향은도전장료적인쇄성화소결성。실험채용사망인쇄공예,재송유순-정기잡필순-을기섬유소체계중첨가송절유、1,4-정내지、감유、린분이갑산이정지사충유궤물조절유궤재체적휘발성,령외탐구재유궤재체중첨가경화비마유、취선알사대유궤재체적촉변성적영향。발현,당송절유=10%、1,4-정내지=15%0、송유순=35%、정기잡필순=10%、병삼순=10%、린분이갑산이정지=10%시용제구유량호적휘발성,휘발균균,피면료집중휘발조성은막기공적산생。령외,당취선알사질량분수위0.4%시,촉변지수위1.9,유궤재체구유교호적촉변성,가유효개선은도전장료적인쇄성。
organic carrier with a level of volatile and good thixotropy affect the printing resistance and sintering of conductive silver paste, screen printing was adopted, and turpentine, 1,4-butyl ester, glycerin and phthalic acid dibutyl were added into terpineol-ethyl cellulose-butyl carbitol system to regulate volatile of organic carrier. And the hydrogenated castor oil and polyamide wax were added in the organic carrier to explore the influence on thixotropy of organic carrier.It was found that when thew(turpentine)= 10%,w(1,4-butyrolactone)=15%,w(terpineol)=35%,w(butyl carbitol)=10%,w(glycerin)=10%,w(phthalic acid dibutyl)=10%, the solvent has good volatile. It can avoids the production of pores on silver film caused by concentrated volatile. In addition, when the mass fraction of polyamide wax is 0.4%, the thixotropic index is 1.9, organic carrier has good thixotropy, which can effectively improve the printing quality of silver conductive paste.