河南科技
河南科技
하남과기
Journal of Henan Science and Technology
2015年
14期
120-123
,共4页
肖进%陈磊%袁洪春%熊超%赵宇%杜文汉%马金祥
肖進%陳磊%袁洪春%熊超%趙宇%杜文漢%馬金祥
초진%진뢰%원홍춘%웅초%조우%두문한%마금상
平板状%固体氧化物燃料电池(SOFC)%氧化钇稳定的氧化锆(YSZ)
平闆狀%固體氧化物燃料電池(SOFC)%氧化釔穩定的氧化鋯(YSZ)
평판상%고체양화물연료전지(SOFC)%양화을은정적양화고(YSZ)
Planar%solid oxide fuel cells (SOFCs)%Yttria-Stabilized Zirconia(YSZ)
通过相转换流延结合浆料涂覆的方法制备了基于YSZ(氧化钇稳定的氧化锆)电解质的阳极支撑的平板固体氧化物燃料电池,电池阳极具有良好的非对称结构,包括较厚的指状大孔层和较薄的海绵状小孔层。以La0.8Sr0.2MnO3-δ-YSZ为阴极,电解质厚度为19μm的单电池获得了良好的性能输出,在600oC,650oC和700oC的最大功率密度分别为52MW/cm2,116MW/cm2和204MW/cm2,对应的开路电压分别为1.04V,1.02V和1.0V。结果表明:相转换流延结合浆料涂覆技术是一种非常有前景的阳极支撑的平板状SOFC制备方法。
通過相轉換流延結閤漿料塗覆的方法製備瞭基于YSZ(氧化釔穩定的氧化鋯)電解質的暘極支撐的平闆固體氧化物燃料電池,電池暘極具有良好的非對稱結構,包括較厚的指狀大孔層和較薄的海綿狀小孔層。以La0.8Sr0.2MnO3-δ-YSZ為陰極,電解質厚度為19μm的單電池穫得瞭良好的性能輸齣,在600oC,650oC和700oC的最大功率密度分彆為52MW/cm2,116MW/cm2和204MW/cm2,對應的開路電壓分彆為1.04V,1.02V和1.0V。結果錶明:相轉換流延結閤漿料塗覆技術是一種非常有前景的暘極支撐的平闆狀SOFC製備方法。
통과상전환류연결합장료도복적방법제비료기우YSZ(양화을은정적양화고)전해질적양겁지탱적평판고체양화물연료전지,전지양겁구유량호적비대칭결구,포괄교후적지상대공층화교박적해면상소공층。이La0.8Sr0.2MnO3-δ-YSZ위음겁,전해질후도위19μm적단전지획득료량호적성능수출,재600oC,650oC화700oC적최대공솔밀도분별위52MW/cm2,116MW/cm2화204MW/cm2,대응적개로전압분별위1.04V,1.02V화1.0V。결과표명:상전환류연결합장료도복기술시일충비상유전경적양겁지탱적평판상SOFC제비방법。
Anode-supported planar solid oxide fuel cells (SOFCs) based on yttria-stabilized zirconia (YSZ) electro?lytes were prepared using phase inversion tape-casting and slurry coating techniques. The anodes of the cells have a good asymmetrical structure consisting of a thick layer with finger-like pores and a thin layer with small sponge-like pores. With La0.8Sr0.2MnO3-δ-YSZ (LSM-YSZ) as a cathode, the maximum power densities of the cell with a 19-μm-thick YSZ electrolyte film reached 52MW/cm2, 116MW/cm2, 206MW/cm2 at 600, 650℃ and 700℃ respectively with a good performance output, and the corresponding open-circuit voltages (OCVs) were 1.04V, 1.02V and 1 V. The results indicate that phase inversion tape-casing combined with slurry coating technique can be considered as a quite promising approach for cost-effective fabrication of anode-supported planar SOFCs.