CAJ | 학술논문

总结了我们在新型炔银簇化合物研究方面的最新进展。这些化合物分为以下几种类型：(a)1,3,5-己三炔基和1,3,5,7-辛四炔基；(b)1,5-己二炔基；(c)经膦酸配体组装的乙炔基和烷基乙炔基；(d)苯乙炔基、环烷基乙炔基和含氮杂环基乙炔基结构单元的银簇化合物；( e)经不同类型的银-碳配位键连接,并进一步通过分子内/分子间作用力稳固其配位网络的炔银化合物。我们还进一步讨论了溶剂、配体的位阻大小和辅助配体类型对于多维配位网络结构的影响。
총결료아문재신형결은족화합물연구방면적최신진전。저사화합물분위이하궤충류형：(a)1,3,5-기삼결기화1,3,5,7-신사결기；(b)1,5-기이결기；(c)경련산배체조장적을결기화완기을결기；(d)분을결기、배완기을결기화함담잡배기을결기결구단원적은족화합물；( e)경불동류형적은-탄배위건련접,병진일보통과분자내/분자간작용력은고기배위망락적결은화합물。아문환진일보토론료용제、배체적위조대소화보조배체류형대우다유배위망락결구적영향。
This review summarizes recent advances conducted by our group on related silver complexes of ( a) all-carbon ligands C2-6 and C2-8 , (b) 1,5-hexadiyne-1,6-diide C6H2-4 , (c) ethynediide C2-2 and ethynide R—C-2 assembled with phosphonic acids, ( d) aryl, alicyclic and heteroaromatic ethynides, and ( e) ethynides that are sta-bilized by different types of silver…carbon binding interactions in the crystalline state, which are further consolidated by weak intra/intermolecular forces. The effects of the solvent, bulkiness of ligands and ancillary ligands on the construction of coordination networks are also discussed.