CAJ | 학술논문

卤键是与氢键相似的一种分子间非共价作用，存在于卤原子的σ反键轨道与具有孤电子对的原子或π电子体系之间，在功能材料与生物药物设计方面发挥了独特作用。介绍卤键的作用本质，阐述卤键发展简史，并描述卤键的基本特征。
서건시여경건상사적일충분자간비공개작용，존재우서원자적σ반건궤도여구유고전자대적원자혹π전자체계지간，재공능재료여생물약물설계방면발휘료독특작용。개소서건적작용본질，천술서건발전간사，병묘술서건적기본특정。
Halogen bonding, a noncovalent, int ermolecular weak interaction analogues to hydrogen bonding, exists between σ antibonding orbital of halogen atoms and atoms with lone-pair electron and πelectron system, which exerts unique effect in the field of desigh of functional materials and biomedicine. In this paper, the interaction essence of halogen bonding was simply introduced, the developing history of halogen bonding was elaborated and the basic character of halogen bonding was depicted, looking forward to much more comprehension toward halogen bonding.