当代化工
噹代化工
당대화공
Contemporary Chemical Industry
2015年
11期
2611-2614
,共4页
安佰龙%乔庆东%李琪%高培玉
安佰龍%喬慶東%李琪%高培玉
안백룡%교경동%리기%고배옥
二茂铁%光活性%光致断裂%三阶非线性光学
二茂鐵%光活性%光緻斷裂%三階非線性光學
이무철%광활성%광치단렬%삼계비선성광학
Ferrocene%Optic activity%Photocleavers%NLO
具有光活性的二茂铁基功能材料以其独特的结构和性质而备受关注。光活性二茂铁衍生物是光动力疗法(Photodynamic Therapy,PDT)治疗癌症的主要成分,因其在杀死癌细胞的同时对机体毒害小,选择性好,可重复治疗等优点备受关注。含有共轭体系的二茂铁衍生物易发生非对称极化,表现出很大的非线性光学(nonlinear optics, NLO)光学响应,是优秀的光电学材料。综述了光活性二茂铁衍生物在 PDT 和非线性光学中的最新研究进展,并对研究方向进行了展望。
具有光活性的二茂鐵基功能材料以其獨特的結構和性質而備受關註。光活性二茂鐵衍生物是光動力療法(Photodynamic Therapy,PDT)治療癌癥的主要成分,因其在殺死癌細胞的同時對機體毒害小,選擇性好,可重複治療等優點備受關註。含有共軛體繫的二茂鐵衍生物易髮生非對稱極化,錶現齣很大的非線性光學(nonlinear optics, NLO)光學響應,是優秀的光電學材料。綜述瞭光活性二茂鐵衍生物在 PDT 和非線性光學中的最新研究進展,併對研究方嚮進行瞭展望。
구유광활성적이무철기공능재료이기독특적결구화성질이비수관주。광활성이무철연생물시광동력요법(Photodynamic Therapy,PDT)치료암증적주요성분,인기재살사암세포적동시대궤체독해소,선택성호,가중복치료등우점비수관주。함유공액체계적이무철연생물역발생비대칭겁화,표현출흔대적비선성광학(nonlinear optics, NLO)광학향응,시우수적광전학재료。종술료광활성이무철연생물재 PDT 화비선성광학중적최신연구진전,병대연구방향진행료전망。
As the functional material, photoactive ferrocene derivatives have attracted a lot of attention because of unique structure and nature. Ferrocene derivatives with optical activity are the main ingredient in PDT to treat cancer, because of its small poison while killing cancer cells of the body, good selectivity,repeatable treatment, and so on.Ferrocene derivatives containing conjugated system easily form asymmetric polarization, show large NLO optics response, so they are excellent photoelectric materials. In this paper, the latest research progress of photoactive ferrocene derivatives in the PDT and nonlinear optics was reviewed, and their research trend in future was forecasted.