CAJ | 학술논문

利用高频电炉对神府煤进行快速热解，研究了不同热解温度和停留时间下，固相和气相产物的性质。结果表明，煤焦的失重率及真密度随温度升高和时间的延长而增长。红外光谱结果表明，热解过程中，煤中含氢/含氧官能团分解，生成H2、CO、CO2、CH4等气体，并且其分解程度随温度的升高和时间的延长而加深。气相产物中H2和CO的释放量随温度的升高和时间的延长而增加，而CO2和CH4存在释放量的峰值。气相产物随温度的升高和时间的延长而增多，导致高温煤焦出现大量的孔隙和裂缝。
이용고빈전로대신부매진행쾌속열해，연구료불동열해온도화정류시간하，고상화기상산물적성질。결과표명，매초적실중솔급진밀도수온도승고화시간적연장이증장。홍외광보결과표명，열해과정중，매중함경/함양관능단분해，생성H2、CO、CO2、CH4등기체，병차기분해정도수온도적승고화시간적연장이가심。기상산물중H2화CO적석방량수온도적승고화시간적연장이증가，이CO2화CH4존재석방량적봉치。기상산물수온도적승고화시간적연장이증다，도치고온매초출현대량적공극화렬봉。
A high-frequency furnace was utilized to carry out rapid pyrolysis of Shenfu coal. The effect of temperature and residence time on the properties of solid and gas products was studied. The results show that the mass loss and true density of the char increase with increasing of both temperature and time. The analysis of their infrared spectra indicates that the hydrogen/oxygen functional groups decompose to form H2 , CO, CO2 , CH4 and other gases during pyrolysis, and the decomposition increase with increasing temperature and time. The emission of H2 and CO monotonically increases, however there are emission peaks for CO2 and CH4 . The total gas products increase with temperature and time, leading to the pores and cracks on the char after high temperature pyrolysis.