天津大学学报（英文版）
天津大學學報（英文版）
천진대학학보（영문판）
Transactions of Tianjin University
2015年
6期
554-561
,共8页
passive film%304 stainless steel%thiosulfate%SIMS%polarization curve
Passivity degradation of 304 stainless steel(SS) in simulated alkaline water chemistries at 300,℃was investigated using polarization curve, scanning electron microscope, time-of-flight secondary ion mass spectrome-try(SIMS) and X-ray photoelectron spectroscopy(XPS). Experimental results indicated that 304,SS was self-passive in the test solution and the thickness of passive film was about 500 nm. Hydroxide was enriched in the outer layer whereas oxide was enriched in the inner layer. Sulfur in thiosulfate could be reduced into lower valence of sulfur and enter the passive film so that the composition of passive film was modified by sulfur. Fe and Cr were enriched in the passive film whereas Ni was depleted in the passive film.
