化工进展
化工進展
화공진전
Chemical Industry and Engineering Progress
2015年
12期
4172-4178
,共7页
余疆江%郑绵平%伍倩%王云生%乜贞%卜令忠
餘疆江%鄭綿平%伍倩%王雲生%乜貞%蔔令忠
여강강%정면평%오천%왕운생%먀정%복령충
气候变化%碳酸盐型%自然蒸发%析盐规律
氣候變化%碳痠鹽型%自然蒸髮%析鹽規律
기후변화%탄산염형%자연증발%석염규률
climatic change%carbonate-type%natural evaporation%crystallization law
湖泊面积扩大和湖水淡化是青藏高原盐湖在响应全球气候变化过程中最直接的一种表现形式,这给青藏高原盐湖资源的开发带来了诸多挑战,探索淡化湖水中可利用元素的富集成矿规律在新形势下越趋重要.本文现场自然蒸发实验以杜佳里淡化碳酸盐型盐湖为研究对象,根据Na+、K+/Cl-、SO42-、CO32--H2O五元体系298K介稳相图,获得了淡化湖水在蒸发过程中Na、K、B、Li元素的富集浓缩规律以及各盐类矿物在蒸发过程中的析出规律.实验结果显示,杜佳里盐湖湖水在自然蒸发过程中最先析出芒硝矿物,其次为含CO32?的碱类矿物,最后析出含B和K的矿物.直至实验结束,未见任何含Li矿物的析出,Li+仍处于浓缩富集过程中.
湖泊麵積擴大和湖水淡化是青藏高原鹽湖在響應全毬氣候變化過程中最直接的一種錶現形式,這給青藏高原鹽湖資源的開髮帶來瞭諸多挑戰,探索淡化湖水中可利用元素的富集成礦規律在新形勢下越趨重要.本文現場自然蒸髮實驗以杜佳裏淡化碳痠鹽型鹽湖為研究對象,根據Na+、K+/Cl-、SO42-、CO32--H2O五元體繫298K介穩相圖,穫得瞭淡化湖水在蒸髮過程中Na、K、B、Li元素的富集濃縮規律以及各鹽類礦物在蒸髮過程中的析齣規律.實驗結果顯示,杜佳裏鹽湖湖水在自然蒸髮過程中最先析齣芒硝礦物,其次為含CO32?的堿類礦物,最後析齣含B和K的礦物.直至實驗結束,未見任何含Li礦物的析齣,Li+仍處于濃縮富集過程中.
호박면적확대화호수담화시청장고원염호재향응전구기후변화과정중최직접적일충표현형식,저급청장고원염호자원적개발대래료제다도전,탐색담화호수중가이용원소적부집성광규률재신형세하월추중요.본문현장자연증발실험이두가리담화탄산염형염호위연구대상,근거Na+、K+/Cl-、SO42-、CO32--H2O오원체계298K개은상도,획득료담화호수재증발과정중Na、K、B、Li원소적부집농축규률이급각염류광물재증발과정중적석출규률.실험결과현시,두가리염호호수재자연증발과정중최선석출망초광물,기차위함CO32?적감류광물,최후석출함B화K적광물.직지실험결속,미견임하함Li광물적석출,Li+잉처우농축부집과정중.
Salt lake expansion is one of the most direct geological responses to the global change on the Qinghai-Tibet Plateau,and the subsequent desalination poses challenges to the exploitation of salt lake resources. For these dilute salt lake,understanding the behavior of enrichment of elements and mineralization has become increasingly important. We carried out natural evaporation experiment on the water of Dujiali salt lake,a representative of dilute carbonate-type salt lake,at a nearby science station. On the basis of the 298K metastable phase diagram for the Na+,K+/Cl?,SO42?,CO32?-H2O quinary system,the concentration behavior of Na,K,B and Li was investigated,and the precipitation conditions and precipitation sequence were reported. Our experiments showed that the precipitation sequence through natural evaporation was mirabilite (Na2SO4·10H2O) the first,carbonate containing alkaline salts the second,and finally B and K bearing minerals. The brine did not reach the stage for the precipitation of Li bearing minerals in our evaporation experiments,and Li+ was enriched in the residual brine.