分析化学
分析化學
분석화학
CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
2001年
2期
202-204
,共3页
张爱梅%王术皓%崔慧
張愛梅%王術皓%崔慧
장애매%왕술호%최혜
亚硝酸根%催化光度法%表面活性剂%吡啰红B
亞硝痠根%催化光度法%錶麵活性劑%吡啰紅B
아초산근%최화광도법%표면활성제%필라홍B
基于稀磷酸介质中,澳化十六烷基吡啶对亚硝酸根催化溴酸钾氧化吡啰红B褪色反应的增敏作用,建立了测定亚硝酸根的表面活性剂增敏催化动力学光度法。加入溴化十六烷基吡啶,灵敏度增大2.2倍。测量亚硝酸根的线性范围为0.005~0.15 mg/L,检出限为0.004mg/L。用于水及蔬菜中痕量亚硝酸根的测定,结果满意。
基于稀燐痠介質中,澳化十六烷基吡啶對亞硝痠根催化溴痠鉀氧化吡啰紅B褪色反應的增敏作用,建立瞭測定亞硝痠根的錶麵活性劑增敏催化動力學光度法。加入溴化十六烷基吡啶,靈敏度增大2.2倍。測量亞硝痠根的線性範圍為0.005~0.15 mg/L,檢齣限為0.004mg/L。用于水及蔬菜中痕量亞硝痠根的測定,結果滿意。
기우희린산개질중,오화십륙완기필정대아초산근최화추산갑양화필라홍B퇴색반응적증민작용,건립료측정아초산근적표면활성제증민최화동역학광도법。가입추화십륙완기필정,령민도증대2.2배。측량아초산근적선성범위위0.005~0.15 mg/L,검출한위0.004mg/L。용우수급소채중흔량아초산근적측정,결과만의。
A catalytic kinetic photometric method for the determination of nitrite with surfactant sensitizer has been developed. The method is based on the catalysis of NO2- to the discoloring reaction of pyronine B oxidized by potassium bromate in the solution of dilute H3PO4. When cetylpyridine bromide was used as a sensitizer of the reaction, the sensitivity increased by 2.5 times approximately. There was linear relationshop of lg(Ao/A) with nitrite in the range 0.005 ~ 0.15 mg/L. The detection limit was 0.004 mg/L. The method was used in the determination of trace nitrite in water and vegetable samples with satisfactory results.